Rotational-translattonal energy exchange in molecule-surface collisions1 1 Supported under R.A. Welch Foundation Grant E-608.

D. E. Fitz; A. O. Bawagan; L. H. Beard; D. J. Kouri; R. B. Gerber

doi:10.1016/0009-2614(81)85073-7

Rotational-translattonal energy exchange in molecule-surface collisions¹ 1 Supported under R.A. Welch Foundation Grant E-608.

D. E. Fitz^*, A. O. Bawagan, L. H. Beard, D. J. Kouri, R. B. Gerber

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

33 Scopus citations

Abstract

Reported are calculations of rotational energy transfer in collisions of Cl₂ molecules with a rigid, smooth surface, using both sudden approximations and quasi-classical trajectories. High probabilities are found for very large Δj transitions compared to corresponding gas-phase collisions: thus molecular collisions with walls can be extremely efficient in producing rotational transitions.

Original language	English
Pages (from-to)	537-540
Number of pages	4
Journal	Chemical Physics Letters
Volume	80
Issue number	3
DOIs	https://doi.org/10.1016/0009-2614(81)85073-7
State	Published - 15 Jun 1981

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title = "Rotational-translattonal energy exchange in molecule-surface collisions1 1 Supported under R.A. Welch Foundation Grant E-608.",

abstract = "Reported are calculations of rotational energy transfer in collisions of Cl2 molecules with a rigid, smooth surface, using both sudden approximations and quasi-classical trajectories. High probabilities are found for very large Δj transitions compared to corresponding gas-phase collisions: thus molecular collisions with walls can be extremely efficient in producing rotational transitions.",

author = "Fitz, \{D. E.\} and Bawagan, \{A. O.\} and Beard, \{L. H.\} and Kouri, \{D. J.\} and Gerber, \{R. B.\}",

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AU - Fitz, D. E.

AU - Bawagan, A. O.

AU - Beard, L. H.

AU - Kouri, D. J.

AU - Gerber, R. B.

PY - 1981/6/15

Y1 - 1981/6/15

N2 - Reported are calculations of rotational energy transfer in collisions of Cl2 molecules with a rigid, smooth surface, using both sudden approximations and quasi-classical trajectories. High probabilities are found for very large Δj transitions compared to corresponding gas-phase collisions: thus molecular collisions with walls can be extremely efficient in producing rotational transitions.

AB - Reported are calculations of rotational energy transfer in collisions of Cl2 molecules with a rigid, smooth surface, using both sudden approximations and quasi-classical trajectories. High probabilities are found for very large Δj transitions compared to corresponding gas-phase collisions: thus molecular collisions with walls can be extremely efficient in producing rotational transitions.

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Rotational-translattonal energy exchange in molecule-surface collisions¹ 1 Supported under R.A. Welch Foundation Grant E-608.

Abstract

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