Self-discharge in flowless Zn-Br2 batteries and its mitigation

Elad Ballas, Amey Nimkar, Gil Bergman, Ran Elazari, Racheli Wakshlak, Daniel Sharon, Mikhael D. Levi, Dan Thomas Major, Daniel Mandler, Netanel Shpigel*, Doron Aurbach

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

1 Scopus citations

Abstract

Several decades after the invention of the flow Zn-Br2 systems, persistent attempts have been made to develop stationary Zn-Br2 batteries. Such development should increase the energy density of the system simultaneously significantly reducing their cost and opening new challenges associated with the cell design and its performance. One of the major concerns is the rapid self-discharge of stationary systems leading to spontaneous charge loss during battery storage time. While self-discharge in flow cells is generally attributed to the chemical oxidation of the Zn anode, we show that the origin of self-discharge in a static configuration is completely different. By systematic investigations of activated carbon with different surface areas under varied charging conditions, mechanistic insights into this phenomenon were provided. Based on this understanding, we proposed herein an effective way to suppress the cathode's self-discharge by encapsulation of a bromine complexing agent inside the electrode's pore matrix. The modified electrodes unveil unique chemical kinetics of deaggregation of the stable fuse salt phase composed of bromine complexing agent and Br3 anions upon discharging. To the best of our knowledge, such a phenomenon has not been reported yet. The proposed system demonstrates high capacity (up to 300 mAh/g) and impressive long-term stability.

Original languageAmerican English
Article number103461
JournalEnergy Storage Materials
Volume70
DOIs
StatePublished - Jun 2024

Bibliographical note

Publisher Copyright:
© 2024 Elsevier B.V.

Keywords

  • Aqueous batteries
  • Flowless Zn-Br batteries
  • Self-discharge
  • Zn batteries
  • Zn-Br batteries

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