Abstract
We have studied a quinary Fe-based superconductor Sr2 VFeAsO3 by the measurements of x-ray diffraction, x-ray absorption, Mössbauer spectrum, resistivity, magnetization, and specific heat. This apparently undoped oxyarsenide is shown to be self-doped via electron transfer from the V3+ ions. We observed successive magnetic transitions within the VO2 layers: an antiferromagnetic transition at 150 K followed by a weak ferromagnetic transition at 55 K. The spin orderings within the VO 2 planes are discussed based on mixed valence of V3+ and V4+.
| Original language | English |
|---|---|
| Article number | 104518 |
| Journal | Physical Review B - Condensed Matter and Materials Physics |
| Volume | 82 |
| Issue number | 10 |
| DOIs | |
| State | Published - 22 Sep 2010 |
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