TY - JOUR
T1 - Simplified time-dependent self-consistent field approximation for intramolecular dynamics
AU - Gerber, R. B.
AU - Ratner, M. A.
AU - Buch, V.
PY - 1982/9/10
Y1 - 1982/9/10
N2 - The time-dependent Hartree approximation is applied to intramolecular dynamics of polyatomics with smooth, locally quadratic potential surfaces. It is shown that the full quantum solution is obtained from a certain single self-consistent trajectory. An extremely simple model results, pertinent to intramolecular energy transfer, vibrational lineshapes and unimolecular decay.
AB - The time-dependent Hartree approximation is applied to intramolecular dynamics of polyatomics with smooth, locally quadratic potential surfaces. It is shown that the full quantum solution is obtained from a certain single self-consistent trajectory. An extremely simple model results, pertinent to intramolecular energy transfer, vibrational lineshapes and unimolecular decay.
UR - http://www.scopus.com/inward/record.url?scp=0002008034&partnerID=8YFLogxK
U2 - 10.1016/0009-2614(82)83635-X
DO - 10.1016/0009-2614(82)83635-X
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AN - SCOPUS:0002008034
SN - 0009-2614
VL - 91
SP - 173
EP - 177
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 3
ER -