TY - JOUR
T1 - Simultaneous High-Purity Enantiomeric Resolution of Conglomerates Using Magnetic Substrates
AU - Bhowmick, Debkumar
AU - Sang, Yutao
AU - Santra, Kakali
AU - Halbauer, Maximilian
AU - Capua, Eyal
AU - Paltiel, Yossi
AU - Naaman, Ron
AU - Tassinari, Francesco
N1 - Publisher Copyright:
©
PY - 2021/5/5
Y1 - 2021/5/5
N2 - Applying magnetic substrates, magnetized perpendicular to the surface, we were able to crystallize from racemic solution pure conglomerates of several molecules. The resolution is based on the spin-dependent charge reorganization (SDCR) effect. By having two surfaces with opposite magnetization, it was possible to simultaneously crystallize on each surface a different enantiomer. The method does not require any seeding or chemical modification and is generally employable to any conglomerate. A system is presented for performing the separation, while the racemic mixture flows between the two magnetic surfaces.
AB - Applying magnetic substrates, magnetized perpendicular to the surface, we were able to crystallize from racemic solution pure conglomerates of several molecules. The resolution is based on the spin-dependent charge reorganization (SDCR) effect. By having two surfaces with opposite magnetization, it was possible to simultaneously crystallize on each surface a different enantiomer. The method does not require any seeding or chemical modification and is generally employable to any conglomerate. A system is presented for performing the separation, while the racemic mixture flows between the two magnetic surfaces.
UR - http://www.scopus.com/inward/record.url?scp=85106444462&partnerID=8YFLogxK
U2 - 10.1021/acs.cgd.1c00093
DO - 10.1021/acs.cgd.1c00093
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AN - SCOPUS:85106444462
SN - 1528-7483
VL - 21
SP - 2925
EP - 2931
JO - Crystal Growth and Design
JF - Crystal Growth and Design
IS - 5
ER -