TY - JOUR
T1 - Sodium chromate oxidation of enol benzoates. Allylic oxidation versus a novel rearrangement
AU - Goldblum, Amiram
AU - Mechoulam, Raphael
PY - 1977
Y1 - 1977
N2 - Various enol benzoates were oxidized with sodium chromate in acetic acid and acetic anhydride. Allylic oxidation (leading to 1 -benzoyloxy-3-0xoalk-l -enes) and a novel oxidative rearrangement (leading to a-benzoyloxyketones) in varying yields were the major reactions observed. The implications of these findings are discussed.
AB - Various enol benzoates were oxidized with sodium chromate in acetic acid and acetic anhydride. Allylic oxidation (leading to 1 -benzoyloxy-3-0xoalk-l -enes) and a novel oxidative rearrangement (leading to a-benzoyloxyketones) in varying yields were the major reactions observed. The implications of these findings are discussed.
UR - http://www.scopus.com/inward/record.url?scp=84918615518&partnerID=8YFLogxK
U2 - 10.1039/P19770001889
DO - 10.1039/P19770001889
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AN - SCOPUS:84918615518
SN - 1470-4358
SP - 1889
EP - 1898
JO - Journal of the Chemical Society, Perkin Transactions 1
JF - Journal of the Chemical Society, Perkin Transactions 1
ER -