Sodium hypochlorite as oxidant in phase transfer catalytic systems. Part II. Oxidation of aromatic alcohols

Sara Abramovici; Ronny Neumann; Yoel Sasson

doi:10.1016/0304-5102(85)80037-7

Sodium hypochlorite as oxidant in phase transfer catalytic systems. Part II. Oxidation of aromatic alcohols

Sara Abramovici^*
, Ronny Neumann
, Yoel Sasson

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

28 Scopus citations

Abstract

Benzyl alcohol was oxidized by aqueous sodium hypochlorite in a phase transfer catalysis reaction catalyzed by quaternary ammonium salts. Two products were obtained, benzaldehyde and benzyl benzoate. The concentration of the organic phase and the pH of the aqueous phase affected the product distribution: a dilute organic phase and low pH favored benzaldehyde as a product, whereas a concentrated organic phase and high pH favored benzyl benzoate as a product.

Original language	English
Pages (from-to)	299-303
Number of pages	5
Journal	Journal of Molecular Catalysis
Volume	29
Issue number	3
DOIs	https://doi.org/10.1016/0304-5102(85)80037-7
State	Published - Apr 1985

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title = "Sodium hypochlorite as oxidant in phase transfer catalytic systems. Part II. Oxidation of aromatic alcohols",

abstract = "Benzyl alcohol was oxidized by aqueous sodium hypochlorite in a phase transfer catalysis reaction catalyzed by quaternary ammonium salts. Two products were obtained, benzaldehyde and benzyl benzoate. The concentration of the organic phase and the pH of the aqueous phase affected the product distribution: a dilute organic phase and low pH favored benzaldehyde as a product, whereas a concentrated organic phase and high pH favored benzyl benzoate as a product.",

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AU - Abramovici, Sara

AU - Neumann, Ronny

AU - Sasson, Yoel

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N2 - Benzyl alcohol was oxidized by aqueous sodium hypochlorite in a phase transfer catalysis reaction catalyzed by quaternary ammonium salts. Two products were obtained, benzaldehyde and benzyl benzoate. The concentration of the organic phase and the pH of the aqueous phase affected the product distribution: a dilute organic phase and low pH favored benzaldehyde as a product, whereas a concentrated organic phase and high pH favored benzyl benzoate as a product.

AB - Benzyl alcohol was oxidized by aqueous sodium hypochlorite in a phase transfer catalysis reaction catalyzed by quaternary ammonium salts. Two products were obtained, benzaldehyde and benzyl benzoate. The concentration of the organic phase and the pH of the aqueous phase affected the product distribution: a dilute organic phase and low pH favored benzaldehyde as a product, whereas a concentrated organic phase and high pH favored benzyl benzoate as a product.

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Sodium hypochlorite as oxidant in phase transfer catalytic systems. Part II. Oxidation of aromatic alcohols

Abstract

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