Solid-liquid equilibrium diagrams of common ion binary salt hydrate mixtures involving nitrates and chlorides of magnesium, cobalt, nickel, manganese, and iron(III)

Y. Marcus*, A. Minevich, L. Ben-Dor

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

5 Scopus citations

Abstract

The solid-liquid equilibrium diagrams of binary mixtures involving magnesium nitrate hexahydrate with cobalt nitrate hexahydrate, nickel nitrate hexahydrate (partly), manganese nitrate tetrahydrate, and iron(III) nitrate nonahydrate and of magnesium chloride hexahydrate with cobalt and nickel chlorides hexahydrates and manganese chloride tetrahydrate, and the of two manganese salts were determined. Those diagrams that showed a simple eutectic were fitted by the Ott equation and where the required BET parameters were available, the magnesium salt rich parts of the liquidus were modeled by means of this method.

Original languageEnglish
Pages (from-to)23-29
Number of pages7
JournalThermochimica Acta
Volume432
Issue number1
DOIs
StatePublished - 1 Jul 2005

Keywords

  • BET modeling
  • Metal chlorides
  • Metal nitrates
  • Phase diagram
  • Salt hydrates

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