Abstract
Using a simplified version of a result due to Kirkwood and Buff, a general formalism is developed for the solute and solvent effect on chemical equilibrium. A specific example-an association reaction-is worked out in some detail to detect the nature of the various factors that combine to induce a shift of the equilibrium in one direction or another.
| Original language | English |
|---|---|
| Pages (from-to) | 2064-2073 |
| Number of pages | 10 |
| Journal | The Journal of Chemical Physics |
| Volume | 63 |
| Issue number | 5 |
| DOIs | |
| State | Published - 1975 |