Abstract
A spectrum-generating algebra for a unified description of rotations and vibrations in polyatomic molecules is introduced. An application to nonlinear X3 molecules shows that this model (i) incorporates exactly the relevant point group, (ii) provides a complete classification of oblate top states, and (iii) treats properly both degenerate and nondegenerate vibrations.
Original language | English |
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Pages (from-to) | 2786-2790 |
Number of pages | 5 |
Journal | Physical Review A |
Volume | 52 |
Issue number | 4 |
DOIs | |
State | Published - 1995 |