Spin-Dependent Enantioselective Electropolymerization

Francesco Tassinari*, Dana Amsallem, Brian P. Bloom, Yiyang Lu, Anjan Bedi, David H. Waldeck, Ori Gidron, Ron Naaman

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

15 Scopus citations

Abstract

The electro-oxidative polymerization of an enantiopure chiral 3,4-ethylenedioxythiophene monomer, performed using spin-polarized currents, is shown to depend on the electron spin orientation. The spin-polarized current is shown to influence the initial nucleation rate of the polymerization reaction. This observation is rationalized in the framework of the chiral-induced spin selectivity effect.

Original languageAmerican English
Pages (from-to)20974-20980
Number of pages7
JournalJournal of Physical Chemistry C
Volume124
Issue number38
DOIs
StatePublished - 24 Sep 2020

Bibliographical note

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Copyright © 2020 American Chemical Society.

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