Spin-Dependent Enantioselective Electropolymerization

Francesco Tassinari; Dana Amsallem; Brian P. Bloom; Yiyang Lu; Anjan Bedi; David H. Waldeck; Ori Gidron; Ron Naaman

doi:10.1021/acs.jpcc.0c06238

Spin-Dependent Enantioselective Electropolymerization

Francesco Tassinari^*
, Dana Amsallem
, Brian P. Bloom
, Yiyang Lu
, Anjan Bedi
, David H. Waldeck
, Ori Gidron
, Ron Naaman

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

The electro-oxidative polymerization of an enantiopure chiral 3,4-ethylenedioxythiophene monomer, performed using spin-polarized currents, is shown to depend on the electron spin orientation. The spin-polarized current is shown to influence the initial nucleation rate of the polymerization reaction. This observation is rationalized in the framework of the chiral-induced spin selectivity effect.

Original language	English
Pages (from-to)	20974-20980
Number of pages	7
Journal	Journal of Physical Chemistry C
Volume	124
Issue number	38
DOIs	https://doi.org/10.1021/acs.jpcc.0c06238
State	Published - 24 Sep 2020

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Copyright © 2020 American Chemical Society.

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abstract = "The electro-oxidative polymerization of an enantiopure chiral 3,4-ethylenedioxythiophene monomer, performed using spin-polarized currents, is shown to depend on the electron spin orientation. The spin-polarized current is shown to influence the initial nucleation rate of the polymerization reaction. This observation is rationalized in the framework of the chiral-induced spin selectivity effect.",

author = "Francesco Tassinari and Dana Amsallem and Bloom, \{Brian P.\} and Yiyang Lu and Anjan Bedi and Waldeck, \{David H.\} and Ori Gidron and Ron Naaman",

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AU - Tassinari, Francesco

AU - Amsallem, Dana

AU - Bloom, Brian P.

AU - Lu, Yiyang

AU - Bedi, Anjan

AU - Waldeck, David H.

AU - Gidron, Ori

AU - Naaman, Ron

PY - 2020/9/24

Y1 - 2020/9/24

N2 - The electro-oxidative polymerization of an enantiopure chiral 3,4-ethylenedioxythiophene monomer, performed using spin-polarized currents, is shown to depend on the electron spin orientation. The spin-polarized current is shown to influence the initial nucleation rate of the polymerization reaction. This observation is rationalized in the framework of the chiral-induced spin selectivity effect.

AB - The electro-oxidative polymerization of an enantiopure chiral 3,4-ethylenedioxythiophene monomer, performed using spin-polarized currents, is shown to depend on the electron spin orientation. The spin-polarized current is shown to influence the initial nucleation rate of the polymerization reaction. This observation is rationalized in the framework of the chiral-induced spin selectivity effect.

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JO - Journal of Physical Chemistry C

JF - Journal of Physical Chemistry C

IS - 38

ER -

Spin-Dependent Enantioselective Electropolymerization

Abstract

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