Spin-Inversion and Orbital Symmetry Conspiracy in Type A Lumiketone Rearrangements

Sason S. Shaik*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

23 Scopus citations

Abstract

Type A lumiketone rearrangement is known to originate from a triplet state1, 2 with evidence suggesting a 3ππ* reactive state. 2b-d The reaction (I) can be viewed as a formal [2π + 2σ].

Original languageEnglish
Pages (from-to)2736-2738
Number of pages3
JournalJournal of the American Chemical Society
Volume101
Issue number10
DOIs
StatePublished - 1979
Externally publishedYes

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