Spin-Inversion and Orbital Symmetry Conspiracy in Type A Lumiketone Rearrangements

Sason S. Shaik

doi:10.1021/ja00504a044

Spin-Inversion and Orbital Symmetry Conspiracy in Type A Lumiketone Rearrangements

Sason S. Shaik^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

Type A lumiketone rearrangement is known to originate from a triplet state^{1, 2} with evidence suggesting a ³ππ* reactive state. 2b-d The reaction (I) can be viewed as a formal [2_π + 2_σ].

Original language	English
Pages (from-to)	2736-2738
Number of pages	3
Journal	Journal of the American Chemical Society
Volume	101
Issue number	10
DOIs	https://doi.org/10.1021/ja00504a044
State	Published - 1979
Externally published	Yes

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title = "Spin-Inversion and Orbital Symmetry Conspiracy in Type A Lumiketone Rearrangements",

abstract = "Type A lumiketone rearrangement is known to originate from a triplet state1, 2 with evidence suggesting a 3ππ* reactive state. 2b-d The reaction (I) can be viewed as a formal [2π + 2σ].",

author = "Shaik, \{Sason S.\}",

year = "1979",

doi = "10.1021/ja00504a044",

language = "אנגלית",

volume = "101",

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journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "10",

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T1 - Spin-Inversion and Orbital Symmetry Conspiracy in Type A Lumiketone Rearrangements

AU - Shaik, Sason S.

PY - 1979

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AB - Type A lumiketone rearrangement is known to originate from a triplet state1, 2 with evidence suggesting a 3ππ* reactive state. 2b-d The reaction (I) can be viewed as a formal [2π + 2σ].

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DO - 10.1021/ja00504a044

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AN - SCOPUS:0039669371

SN - 0002-7863

VL - 101

SP - 2736

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 10

ER -

Spin-Inversion and Orbital Symmetry Conspiracy in Type A Lumiketone Rearrangements

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