TY - JOUR
T1 - Stability of hemi-bonded vs proton-transferred structures of (H2O)2+, (H2S)2+, and (H2Se)2+ studied with projected hartree-fock methods
AU - Stein, Tamar
AU - Jiménez-Hoyos, Carlos A.
AU - Scuseria, Gustavo E.
N1 - Publisher Copyright:
© 2014 American Chemical Society.
PY - 2014/9/4
Y1 - 2014/9/4
N2 - Hartree-Fock (HF) is known to suffer from drawbacks in the description of the relative stabilities between the hemi-bonded (HB) and proton-transferred (PT) isomers of the water dimer cation, (H2O)2+. The energy difference predicted by HF is too large, approximately 27 kcal/mol, which is lowered to 7 kcal/mol when correlation effects are added. The error in HF has been previously attributed to the large dynamic correlation effects in the HB structure as well to the large symmetry breaking this structure exhibits. In this study we use the recently developed projected Hartree-Fock (PHF) methods to study the relative stability of the two isomers of (H2O)2+ as well as its second and third row analogs, namely, (H2S)2+ and (H2Se)2+. In PHF, symmetries are broken and restored in a variation-afterprojection approach and thus can deal easily with systems for which HF itself spontaneously breaks symmetry. We use different flavors of PHF (SUHF, KSUHF, SGHF, and KSGHF) to explore their ability in capturing dynamic correlation effects and to compare their performance to different wave function based methods. We study the role of the symmetry-breaking in the above systems, using wave function based methods with unrestricted and restricted wave functions as well as performing a single-shot symmetry restoration (a projection-after-variation scheme). (Chemical Equation Presented).
AB - Hartree-Fock (HF) is known to suffer from drawbacks in the description of the relative stabilities between the hemi-bonded (HB) and proton-transferred (PT) isomers of the water dimer cation, (H2O)2+. The energy difference predicted by HF is too large, approximately 27 kcal/mol, which is lowered to 7 kcal/mol when correlation effects are added. The error in HF has been previously attributed to the large dynamic correlation effects in the HB structure as well to the large symmetry breaking this structure exhibits. In this study we use the recently developed projected Hartree-Fock (PHF) methods to study the relative stability of the two isomers of (H2O)2+ as well as its second and third row analogs, namely, (H2S)2+ and (H2Se)2+. In PHF, symmetries are broken and restored in a variation-afterprojection approach and thus can deal easily with systems for which HF itself spontaneously breaks symmetry. We use different flavors of PHF (SUHF, KSUHF, SGHF, and KSGHF) to explore their ability in capturing dynamic correlation effects and to compare their performance to different wave function based methods. We study the role of the symmetry-breaking in the above systems, using wave function based methods with unrestricted and restricted wave functions as well as performing a single-shot symmetry restoration (a projection-after-variation scheme). (Chemical Equation Presented).
UR - http://www.scopus.com/inward/record.url?scp=84907407868&partnerID=8YFLogxK
U2 - 10.1021/jp410713d
DO - 10.1021/jp410713d
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C2 - 24437943
AN - SCOPUS:84907407868
SN - 1089-5639
VL - 118
SP - 7261
EP - 7266
JO - Journal of Physical Chemistry A
JF - Journal of Physical Chemistry A
IS - 35
ER -