Standard thermodynamic functions of some isolated ions at 100-1000 K

A. Loewenschuss; Y. Marcus

doi:10.1063/1.555990

Standard thermodynamic functions of some isolated ions at 100-1000 K

A. Loewenschuss^*, Y. Marcus

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

The standard thermodynamic functions (C°_p, S°, H° and (G°-H°₀)/T) at 100 to 1000 K of 24 polyatomic gaseous ions are reported, based on structural and spectroscopic data from the literature. These ions supplement the 130 ions previously studied and are: zirconyl, hydrotelluride, amide, selenocyanate, tellurocyanate, orthoborate, metaphosphate, arsenite, orthosilicate, tetrachloropalladate(II), tetrabromopalladate(II), tetrachloroplatinate(II), tetrabromoplatinate(II), hexafluorophosphate, hexafluoroarsenate, hexafluoroantimonate, hexabromoplatinate(IV), tetracyanonickelate, tetracyanomercurate, octacyanomolybdate(IV), sulfamate, benzoate, guanidinium, and glycine as cation, zwitterion, and anion.

Original language	English
Pages (from-to)	1495-1507
Number of pages	13
Journal	Journal of Physical and Chemical Reference Data
Volume	25
Issue number	6
DOIs	https://doi.org/10.1063/1.555990
State	Published - 1996

Keywords

Bond lengths and angles
Enthalpy of ions
Entropy of ions
Gibbs energy function of ions
Heat capacity of ions
Isolated ions
Thermodynamic functions
Vibrational spectra

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10.1063/1.555990

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title = "Standard thermodynamic functions of some isolated ions at 100-1000 K",

abstract = "The standard thermodynamic functions (C°p, S°, H° and (G°-H°0)/T) at 100 to 1000 K of 24 polyatomic gaseous ions are reported, based on structural and spectroscopic data from the literature. These ions supplement the 130 ions previously studied and are: zirconyl, hydrotelluride, amide, selenocyanate, tellurocyanate, orthoborate, metaphosphate, arsenite, orthosilicate, tetrachloropalladate(II), tetrabromopalladate(II), tetrachloroplatinate(II), tetrabromoplatinate(II), hexafluorophosphate, hexafluoroarsenate, hexafluoroantimonate, hexabromoplatinate(IV), tetracyanonickelate, tetracyanomercurate, octacyanomolybdate(IV), sulfamate, benzoate, guanidinium, and glycine as cation, zwitterion, and anion.",

keywords = "Bond lengths and angles, Enthalpy of ions, Entropy of ions, Gibbs energy function of ions, Heat capacity of ions, Isolated ions, Thermodynamic functions, Vibrational spectra",

author = "A. Loewenschuss and Y. Marcus",

year = "1996",

doi = "10.1063/1.555990",

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AU - Loewenschuss, A.

AU - Marcus, Y.

PY - 1996

Y1 - 1996

N2 - The standard thermodynamic functions (C°p, S°, H° and (G°-H°0)/T) at 100 to 1000 K of 24 polyatomic gaseous ions are reported, based on structural and spectroscopic data from the literature. These ions supplement the 130 ions previously studied and are: zirconyl, hydrotelluride, amide, selenocyanate, tellurocyanate, orthoborate, metaphosphate, arsenite, orthosilicate, tetrachloropalladate(II), tetrabromopalladate(II), tetrachloroplatinate(II), tetrabromoplatinate(II), hexafluorophosphate, hexafluoroarsenate, hexafluoroantimonate, hexabromoplatinate(IV), tetracyanonickelate, tetracyanomercurate, octacyanomolybdate(IV), sulfamate, benzoate, guanidinium, and glycine as cation, zwitterion, and anion.

AB - The standard thermodynamic functions (C°p, S°, H° and (G°-H°0)/T) at 100 to 1000 K of 24 polyatomic gaseous ions are reported, based on structural and spectroscopic data from the literature. These ions supplement the 130 ions previously studied and are: zirconyl, hydrotelluride, amide, selenocyanate, tellurocyanate, orthoborate, metaphosphate, arsenite, orthosilicate, tetrachloropalladate(II), tetrabromopalladate(II), tetrachloroplatinate(II), tetrabromoplatinate(II), hexafluorophosphate, hexafluoroarsenate, hexafluoroantimonate, hexabromoplatinate(IV), tetracyanonickelate, tetracyanomercurate, octacyanomolybdate(IV), sulfamate, benzoate, guanidinium, and glycine as cation, zwitterion, and anion.

KW - Bond lengths and angles

KW - Enthalpy of ions

KW - Entropy of ions

KW - Gibbs energy function of ions

KW - Heat capacity of ions

KW - Isolated ions

KW - Thermodynamic functions

KW - Vibrational spectra

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JO - Journal of Physical and Chemical Reference Data

JF - Journal of Physical and Chemical Reference Data

IS - 6

ER -

Standard thermodynamic functions of some isolated ions at 100-1000 K

Abstract

Keywords

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