Stark energy levels of symmetric-top molecules: An elementary algebraic treatment

B. L. Burrows; M. Cohen; Tova Feldmann

doi:10.1088/0953-4075/28/19/010

Stark energy levels of symmetric-top molecules: An elementary algebraic treatment

B. L. Burrows
, M. Cohen
, Tova Feldmann

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

We derive simple semi-analytical expressions for the Stark energy levels of a general symmetric-top molecule placed in a uniform electric field of arbitrary strength. These are obtained by means of third-order perturbation theory following a suitable canonical transformation of the system Hamiltonian, which is conveniently written in terms of the generators of either of the Lie algebras 5(9(3) or 50(2, 1).

Original language	English
Pages (from-to)	4249-4257
Number of pages	9
Journal	Journal of Physics B: Atomic, Molecular and Optical Physics
Volume	28
Issue number	19
DOIs	https://doi.org/10.1088/0953-4075/28/19/010
State	Published - 14 Oct 1995

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title = "Stark energy levels of symmetric-top molecules: An elementary algebraic treatment",

abstract = "We derive simple semi-analytical expressions for the Stark energy levels of a general symmetric-top molecule placed in a uniform electric field of arbitrary strength. These are obtained by means of third-order perturbation theory following a suitable canonical transformation of the system Hamiltonian, which is conveniently written in terms of the generators of either of the Lie algebras 5(9(3) or 50(2, 1).",

author = "Burrows, \{B. L.\} and M. Cohen and Tova Feldmann",

year = "1995",

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doi = "10.1088/0953-4075/28/19/010",

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T1 - Stark energy levels of symmetric-top molecules

T2 - An elementary algebraic treatment

AU - Burrows, B. L.

AU - Cohen, M.

AU - Feldmann, Tova

PY - 1995/10/14

Y1 - 1995/10/14

N2 - We derive simple semi-analytical expressions for the Stark energy levels of a general symmetric-top molecule placed in a uniform electric field of arbitrary strength. These are obtained by means of third-order perturbation theory following a suitable canonical transformation of the system Hamiltonian, which is conveniently written in terms of the generators of either of the Lie algebras 5(9(3) or 50(2, 1).

AB - We derive simple semi-analytical expressions for the Stark energy levels of a general symmetric-top molecule placed in a uniform electric field of arbitrary strength. These are obtained by means of third-order perturbation theory following a suitable canonical transformation of the system Hamiltonian, which is conveniently written in terms of the generators of either of the Lie algebras 5(9(3) or 50(2, 1).

UR - https://www.scopus.com/pages/publications/2742568168

U2 - 10.1088/0953-4075/28/19/010

DO - 10.1088/0953-4075/28/19/010

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AN - SCOPUS:2742568168

SN - 0953-4075

VL - 28

SP - 4249

EP - 4257

JO - Journal of Physics B: Atomic, Molecular and Optical Physics

JF - Journal of Physics B: Atomic, Molecular and Optical Physics

IS - 19

ER -

Stark energy levels of symmetric-top molecules: An elementary algebraic treatment

Abstract

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