TY - JOUR
T1 - Statistical mechanical study of hydrophobie interaction. iv. the behavior of the function y(R) at short distances
AU - Ben-Naim, A.
PY - 1972
Y1 - 1972
N2 - The function [A. Ben-Nairn, J. Chem. Phys. 54, 1387, 3696 (1971)] y(R)=exp[-δAHI(R)], playing a central role in the theory of solute-solute interaction, is shown to be a monotonous decreasing function of R at short distances. A formal proof is given for two hard cube solutes approaching along a particular line. Further evidence, based on the Percus-Yevick equations for a two-dimensional system of spherical solutes, is provided.
AB - The function [A. Ben-Nairn, J. Chem. Phys. 54, 1387, 3696 (1971)] y(R)=exp[-δAHI(R)], playing a central role in the theory of solute-solute interaction, is shown to be a monotonous decreasing function of R at short distances. A formal proof is given for two hard cube solutes approaching along a particular line. Further evidence, based on the Percus-Yevick equations for a two-dimensional system of spherical solutes, is provided.
UR - http://www.scopus.com/inward/record.url?scp=36849109565&partnerID=8YFLogxK
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AN - SCOPUS:36849109565
SN - 0021-9606
VL - 57
SP - 5270
EP - 5276
JO - The Journal of Chemical Physics
JF - The Journal of Chemical Physics
IS - 12
ER -