Abstract
The function [A. Ben-Nairn, J. Chem. Phys. 54, 1387, 3696 (1971)] y(R)=exp[-δAHI(R)], playing a central role in the theory of solute-solute interaction, is shown to be a monotonous decreasing function of R at short distances. A formal proof is given for two hard cube solutes approaching along a particular line. Further evidence, based on the Percus-Yevick equations for a two-dimensional system of spherical solutes, is provided.
| Original language | English |
|---|---|
| Pages (from-to) | 5270-5276 |
| Number of pages | 7 |
| Journal | The Journal of Chemical Physics |
| Volume | 57 |
| Issue number | 12 |
| State | Published - 1972 |
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