Statistical wavefunction method for highly excited vibrational states of polyatomic molecules

R. B. Gerber; Victoria Buch; M. A. Ratner

doi:10.1016/0009-2614(82)83396-4

Statistical wavefunction method for highly excited vibrational states of polyatomic molecules

R. B. Gerber^*
, Victoria Buch
, M. A. Ratner

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

An approximation is proposed for calculations of average properties of high-lying vibrational states of polyatomics. The method employs a statistical model for the wavefunctions. The approximation was tested against exact, extensive numerical results for transition moment distributions in two-mode model systems. Good agreement was found.

Original language	English
Pages (from-to)	171-173
Number of pages	3
Journal	Chemical Physics Letters
Volume	89
Issue number	2
DOIs	https://doi.org/10.1016/0009-2614(82)83396-4
State	Published - 11 Jun 1982
Externally published	Yes

Access to Document

10.1016/0009-2614(82)83396-4

Cite this

@article{c128a8d4793849c4b9cb14d127c56778,

title = "Statistical wavefunction method for highly excited vibrational states of polyatomic molecules",

abstract = "An approximation is proposed for calculations of average properties of high-lying vibrational states of polyatomics. The method employs a statistical model for the wavefunctions. The approximation was tested against exact, extensive numerical results for transition moment distributions in two-mode model systems. Good agreement was found.",

author = "Gerber, \{R. B.\} and Victoria Buch and Ratner, \{M. A.\}",

year = "1982",

month = jun,

day = "11",

doi = "10.1016/0009-2614(82)83396-4",

language = "אנגלית",

volume = "89",

pages = "171--173",

journal = "Chemical Physics Letters",

issn = "0009-2614",

publisher = "Elsevier B.V.",

number = "2",

}

TY - JOUR

T1 - Statistical wavefunction method for highly excited vibrational states of polyatomic molecules

AU - Gerber, R. B.

AU - Buch, Victoria

AU - Ratner, M. A.

PY - 1982/6/11

Y1 - 1982/6/11

N2 - An approximation is proposed for calculations of average properties of high-lying vibrational states of polyatomics. The method employs a statistical model for the wavefunctions. The approximation was tested against exact, extensive numerical results for transition moment distributions in two-mode model systems. Good agreement was found.

AB - An approximation is proposed for calculations of average properties of high-lying vibrational states of polyatomics. The method employs a statistical model for the wavefunctions. The approximation was tested against exact, extensive numerical results for transition moment distributions in two-mode model systems. Good agreement was found.

UR - https://www.scopus.com/pages/publications/49049137054

U2 - 10.1016/0009-2614(82)83396-4

DO - 10.1016/0009-2614(82)83396-4

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

AN - SCOPUS:49049137054

SN - 0009-2614

VL - 89

SP - 171

EP - 173

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 2

ER -

Statistical wavefunction method for highly excited vibrational states of polyatomic molecules

Abstract

Access to Document

Other files and links

Fingerprint

Cite this