Steady state multiplicity of electrochemical reactions due to negative stoichiometric diffusivity

Ovadia Lev; L. M. Pismen

doi:10.1016/0013-4686(86)80108-6

Steady state multiplicity of electrochemical reactions due to negative stoichiometric diffusivity

Ovadia Lev, L. M. Pismen^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Inverse voltage-current relationships and multiple steady states can be caused by negative "stoichiometric diffusivity" of an ionic solution in certain electrode reactions, which results in a reversal of the direction of the potential gradient in the diffusional layer. We give several simple examples of this effect.

Original language	English
Pages (from-to)	451-455
Number of pages	5
Journal	Electrochimica Acta
Volume	31
Issue number	4
DOIs	https://doi.org/10.1016/0013-4686(86)80108-6
State	Published - Apr 1986
Externally published	Yes

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title = "Steady state multiplicity of electrochemical reactions due to negative stoichiometric diffusivity",

abstract = "Inverse voltage-current relationships and multiple steady states can be caused by negative {"}stoichiometric diffusivity{"} of an ionic solution in certain electrode reactions, which results in a reversal of the direction of the potential gradient in the diffusional layer. We give several simple examples of this effect.",

author = "Ovadia Lev and Pismen, \{L. M.\}",

year = "1986",

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AU - Lev, Ovadia

AU - Pismen, L. M.

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N2 - Inverse voltage-current relationships and multiple steady states can be caused by negative "stoichiometric diffusivity" of an ionic solution in certain electrode reactions, which results in a reversal of the direction of the potential gradient in the diffusional layer. We give several simple examples of this effect.

AB - Inverse voltage-current relationships and multiple steady states can be caused by negative "stoichiometric diffusivity" of an ionic solution in certain electrode reactions, which results in a reversal of the direction of the potential gradient in the diffusional layer. We give several simple examples of this effect.

UR - https://www.scopus.com/pages/publications/0022707125

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SN - 0013-4686

VL - 31

SP - 451

EP - 455

JO - Electrochimica Acta

JF - Electrochimica Acta

IS - 4

ER -

Steady state multiplicity of electrochemical reactions due to negative stoichiometric diffusivity

Abstract

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