Stereochemistry of Hydroboration of Methylenecyclohexanes

J. Klein; D. Lichtenberg

doi:10.1021/jo00833a037

Stereochemistry of Hydroboration of Methylenecyclohexanes

J. Klein, D. Lichtenberg

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Abstract

Hydroboration of 3- and 4-methyl- and 3- and 4-t-butylmethylenecyelohexanes yielded, after oxidation, predominantly the axial-equatorial disubstituted cyclohexanes. Similar results were obtained when dichloroborane was used as the hydroborating agent. Dicyclohexylborane gave equal amounts of axial and equatorial products.

Original language	English
Pages (from-to)	2654-2656
Number of pages	3
Journal	Journal of Organic Chemistry
Volume	35
Issue number	8
DOIs	https://doi.org/10.1021/jo00833a037
State	Published - 1 Aug 1970

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title = "Stereochemistry of Hydroboration of Methylenecyclohexanes",

abstract = "Hydroboration of 3- and 4-methyl- and 3- and 4-t-butylmethylenecyelohexanes yielded, after oxidation, predominantly the axial-equatorial disubstituted cyclohexanes. Similar results were obtained when dichloroborane was used as the hydroborating agent. Dicyclohexylborane gave equal amounts of axial and equatorial products.",

author = "J. Klein and D. Lichtenberg",

year = "1970",

month = aug,

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doi = "10.1021/jo00833a037",

language = "אנגלית",

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journal = "Journal of Organic Chemistry",

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T1 - Stereochemistry of Hydroboration of Methylenecyclohexanes

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AU - Lichtenberg, D.

PY - 1970/8/1

Y1 - 1970/8/1

N2 - Hydroboration of 3- and 4-methyl- and 3- and 4-t-butylmethylenecyelohexanes yielded, after oxidation, predominantly the axial-equatorial disubstituted cyclohexanes. Similar results were obtained when dichloroborane was used as the hydroborating agent. Dicyclohexylborane gave equal amounts of axial and equatorial products.

AB - Hydroboration of 3- and 4-methyl- and 3- and 4-t-butylmethylenecyelohexanes yielded, after oxidation, predominantly the axial-equatorial disubstituted cyclohexanes. Similar results were obtained when dichloroborane was used as the hydroborating agent. Dicyclohexylborane gave equal amounts of axial and equatorial products.

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SP - 2654

EP - 2656

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 8

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Stereochemistry of Hydroboration of Methylenecyclohexanes

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