Stereochemistry of polyethylated aromatic systems

Vered Marks; Hugo E. Gottlieb; Silvio E. Biali

doi:10.1002/ejoc.200200580

Stereochemistry of polyethylated aromatic systems

Vered Marks, Hugo E. Gottlieb^*, Silvio E. Biali

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Short survey › peer-review

2 Scopus citations

Abstract

Hexaethylbenzene adopts a conformation with the ethyl groups perpendicular to the aromatic ring and oriented in a fully alternated up-down arrangement. The synthesis, stereochemistry and rotational barriers of systems possessing two polyethylaryl rings in spatial proximity (e.g., decaethylbiphenyl, octaethylbiphenylene) are reviewed.

Original language	English
Pages (from-to)	1825-1835
Number of pages	11
Journal	European Journal of Organic Chemistry
Issue number	10
DOIs	https://doi.org/10.1002/ejoc.200200580
State	Published - May 2003

Keywords

Arenes
Arynes
Biaryls
Stereochemistry
Steric hindrance

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10.1002/ejoc.200200580

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title = "Stereochemistry of polyethylated aromatic systems",

abstract = "Hexaethylbenzene adopts a conformation with the ethyl groups perpendicular to the aromatic ring and oriented in a fully alternated up-down arrangement. The synthesis, stereochemistry and rotational barriers of systems possessing two polyethylaryl rings in spatial proximity (e.g., decaethylbiphenyl, octaethylbiphenylene) are reviewed.",

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AU - Biali, Silvio E.

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AB - Hexaethylbenzene adopts a conformation with the ethyl groups perpendicular to the aromatic ring and oriented in a fully alternated up-down arrangement. The synthesis, stereochemistry and rotational barriers of systems possessing two polyethylaryl rings in spatial proximity (e.g., decaethylbiphenyl, octaethylbiphenylene) are reviewed.

KW - Arenes

KW - Arynes

KW - Biaryls

KW - Stereochemistry

KW - Steric hindrance

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Stereochemistry of polyethylated aromatic systems

Abstract

Keywords

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