Structural aspects of water in 1-octanol

Y. Marcus

doi:10.1007/BF00650383

Structural aspects of water in 1-octanol

Y. Marcus^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

33 Scopus citations

Abstract

Water-saturated 1-octanol, extensively used for studies of the distribution of organic solutes, is subjected to structural analysis in terms of the neighbors each molecule has. This is based on thermodynamic information on the system from the literature. The local composition of a given water molecule is richer in water than the bulk composition, and, conversely, for the local composition near a 1-octanol molecule. At saturation (mole fraction of water of 0.275 in the organic phase) the excess (deficiency) of the mole fraction of water is 0.197 (-0.075) near water (1-octanol) molecules.

Original language	English
Pages (from-to)	507-517
Number of pages	11
Journal	Journal of Solution Chemistry
Volume	19
Issue number	5
DOIs	https://doi.org/10.1007/BF00650383
State	Published - May 1990

Keywords

1-Octanol
aqueous mixtures
structure

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10.1007/BF00650383

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title = "Structural aspects of water in 1-octanol",

abstract = "Water-saturated 1-octanol, extensively used for studies of the distribution of organic solutes, is subjected to structural analysis in terms of the neighbors each molecule has. This is based on thermodynamic information on the system from the literature. The local composition of a given water molecule is richer in water than the bulk composition, and, conversely, for the local composition near a 1-octanol molecule. At saturation (mole fraction of water of 0.275 in the organic phase) the excess (deficiency) of the mole fraction of water is 0.197 (-0.075) near water (1-octanol) molecules.",

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AB - Water-saturated 1-octanol, extensively used for studies of the distribution of organic solutes, is subjected to structural analysis in terms of the neighbors each molecule has. This is based on thermodynamic information on the system from the literature. The local composition of a given water molecule is richer in water than the bulk composition, and, conversely, for the local composition near a 1-octanol molecule. At saturation (mole fraction of water of 0.275 in the organic phase) the excess (deficiency) of the mole fraction of water is 0.197 (-0.075) near water (1-octanol) molecules.

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Structural aspects of water in 1-octanol

Abstract

Keywords

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