TY - JOUR
T1 - Structural Considerations in Chemical Kinetics
T2 - Gas Phase H‐Atom Transfer Reaction Series
AU - Agmon, N.
AU - Levine, R. D.
PY - 1980
Y1 - 1980
N2 - Structure–reactivity correlations are discussed and applied to the X + H2 → XH + H and Cl + HX → ClH + X series of gas phase reactions where X is a halogen atom. In particular, potential energy surfaces for the (collinear) XH2 system are obtained in terms of the diatomic, H2 and XH, potentials and two parameters which are common to all members of the series. These surfaces are in quantitative accord with the Evans–Polanyi, Leffler and Hammond postulates. The rate constants satisfy the reactivity‐selectivity principle.
AB - Structure–reactivity correlations are discussed and applied to the X + H2 → XH + H and Cl + HX → ClH + X series of gas phase reactions where X is a halogen atom. In particular, potential energy surfaces for the (collinear) XH2 system are obtained in terms of the diatomic, H2 and XH, potentials and two parameters which are common to all members of the series. These surfaces are in quantitative accord with the Evans–Polanyi, Leffler and Hammond postulates. The rate constants satisfy the reactivity‐selectivity principle.
UR - http://www.scopus.com/inward/record.url?scp=84985123296&partnerID=8YFLogxK
U2 - 10.1002/ijch.198000041
DO - 10.1002/ijch.198000041
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AN - SCOPUS:84985123296
SN - 0021-2148
VL - 19
SP - 330
EP - 336
JO - Israel Journal of Chemistry
JF - Israel Journal of Chemistry
IS - 1-4
ER -