Structural influence on the excimer emission from a dimorphic crystalline stilbene

R. Cohen; Z. Ludmer; V. Yakhot

doi:10.1016/0009-2614(75)85271-7

Structural influence on the excimer emission from a dimorphic crystalline stilbene

R. Cohen^*, Z. Ludmer, V. Yakhot

^*Corresponding author for this work

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Abstract

The compound 2,4-dichloro-3′-methyl-trans-stilbene is dimorphic. The two forms are assigned "pair" and "stack" crystal structures on the basis of their cell dimensions and of the structures of the photodimers derived from them. Excimer emission is observed from both forms, with that from the stack structure being of higher energy. This is in keeping with an earlier theoretical analysis and argues for the validity and generality of this analysis.

Original language	English
Pages (from-to)	271-274
Number of pages	4
Journal	Chemical Physics Letters
Volume	34
Issue number	2
DOIs	https://doi.org/10.1016/0009-2614(75)85271-7
State	Published - 15 Jul 1975
Externally published	Yes

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N2 - The compound 2,4-dichloro-3′-methyl-trans-stilbene is dimorphic. The two forms are assigned "pair" and "stack" crystal structures on the basis of their cell dimensions and of the structures of the photodimers derived from them. Excimer emission is observed from both forms, with that from the stack structure being of higher energy. This is in keeping with an earlier theoretical analysis and argues for the validity and generality of this analysis.

AB - The compound 2,4-dichloro-3′-methyl-trans-stilbene is dimorphic. The two forms are assigned "pair" and "stack" crystal structures on the basis of their cell dimensions and of the structures of the photodimers derived from them. Excimer emission is observed from both forms, with that from the stack structure being of higher energy. This is in keeping with an earlier theoretical analysis and argues for the validity and generality of this analysis.

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Structural influence on the excimer emission from a dimorphic crystalline stilbene

Abstract

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