Structure and reactivity of 2-hydroxyiminobenzyl-2-oxo-4,4,5,5-tetramethyl[1,3,2]dioxaphospholanes

E. Breuer; R. Karaman; D. Gibson; A. Goldblum

doi:10.1080/10426508908039733

Structure and reactivity of 2-hydroxyiminobenzyl-2-oxo-4,4,5,5-tetramethyl[1,3,2]dioxaphospholanes

E. Breuer^*
, R. Karaman
, D. Gibson
, A. Goldblum

^*Corresponding author for this work

School of Pharmacy

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

The reaction of 2-benzoyl-2-oxo-4, 4, 5, 5-tetramethyl [1,3,2] dioxaphospholane (3) with hydroxylamine yields the corresponding E oxime (E-4) and benzonitrile (5), which arises from fragmentation of the Z oxime via an intramolecular attack of the N-OH on the phosphorus.

Original language	English
Pages (from-to)	433-437
Number of pages	5
Journal	Phosphorus, Sulfur and Silicon and the Related Elements
Volume	41
Issue number	3-4
DOIs	https://doi.org/10.1080/10426508908039733
State	Published - 1 Feb 1989

Access to Document

10.1080/10426508908039733

Cite this

@article{5930b3b7dd034837be3c7564e54c3f68,

title = "Structure and reactivity of 2-hydroxyiminobenzyl-2-oxo-4,4,5,5-tetramethyl[1,3,2]dioxaphospholanes",

abstract = "The reaction of 2-benzoyl-2-oxo-4, 4, 5, 5-tetramethyl [1,3,2] dioxaphospholane (3) with hydroxylamine yields the corresponding E oxime (E-4) and benzonitrile (5), which arises from fragmentation of the Z oxime via an intramolecular attack of the N-OH on the phosphorus.",

author = "E. Breuer and R. Karaman and D. Gibson and A. Goldblum",

year = "1989",

month = feb,

day = "1",

doi = "10.1080/10426508908039733",

language = "אנגלית",

volume = "41",

pages = "433--437",

journal = "Phosphorus, Sulfur and Silicon and the Related Elements",

issn = "1042-6507",

publisher = "Taylor and Francis Ltd.",

number = "3-4",

}

TY - JOUR

T1 - Structure and reactivity of 2-hydroxyiminobenzyl-2-oxo-4,4,5,5-tetramethyl[1,3,2]dioxaphospholanes

AU - Breuer, E.

AU - Karaman, R.

AU - Gibson, D.

AU - Goldblum, A.

PY - 1989/2/1

Y1 - 1989/2/1

N2 - The reaction of 2-benzoyl-2-oxo-4, 4, 5, 5-tetramethyl [1,3,2] dioxaphospholane (3) with hydroxylamine yields the corresponding E oxime (E-4) and benzonitrile (5), which arises from fragmentation of the Z oxime via an intramolecular attack of the N-OH on the phosphorus.

AB - The reaction of 2-benzoyl-2-oxo-4, 4, 5, 5-tetramethyl [1,3,2] dioxaphospholane (3) with hydroxylamine yields the corresponding E oxime (E-4) and benzonitrile (5), which arises from fragmentation of the Z oxime via an intramolecular attack of the N-OH on the phosphorus.

UR - https://www.scopus.com/pages/publications/84973065376

U2 - 10.1080/10426508908039733

DO - 10.1080/10426508908039733

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

AN - SCOPUS:84973065376

SN - 1042-6507

VL - 41

SP - 433

EP - 437

JO - Phosphorus, Sulfur and Silicon and the Related Elements

JF - Phosphorus, Sulfur and Silicon and the Related Elements

IS - 3-4

ER -

Structure and reactivity of 2-hydroxyiminobenzyl-2-oxo-4,4,5,5-tetramethyl[1,3,2]dioxaphospholanes

Abstract

Access to Document

Other files and links

Fingerprint

Cite this