TY - JOUR
T1 - Studies in mass spectrometry. Part XIV. The effect of conformation on the electron impact-induced fragmentation of adducts of p-benzoquinone and 1,1′-bicycloalkenyls
AU - Deutsch, Joseph
AU - Mandelbaum, Asher
PY - 1971
Y1 - 1971
N2 - Electron impact-induced double hydrogen migration leading to the formation of ions a from adducts of p-benzoquinone and 1,1′-bicycloalken-1-yls has been found to be suppressed when the sizes of rings c and D of the adducts are increased. This effect is explained in terms of different distances between the migrating hydrogen atoms and the carbonyl groups, which are affected by the conformations of the central ring B and of rings C and D.
AB - Electron impact-induced double hydrogen migration leading to the formation of ions a from adducts of p-benzoquinone and 1,1′-bicycloalken-1-yls has been found to be suppressed when the sizes of rings c and D of the adducts are increased. This effect is explained in terms of different distances between the migrating hydrogen atoms and the carbonyl groups, which are affected by the conformations of the central ring B and of rings C and D.
UR - http://www.scopus.com/inward/record.url?scp=37049121407&partnerID=8YFLogxK
U2 - 10.1039/J29710000886
DO - 10.1039/J29710000886
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AN - SCOPUS:37049121407
SN - 0045-6470
SP - 886
EP - 889
JO - Journal of the Chemical Society B: Physical Organic
JF - Journal of the Chemical Society B: Physical Organic
ER -