Study of the interaction mechanism of 2,2′-bipyridine with the silver surface of model systems by SERS method

Valery Zakharov*, Andrei Rumiantcev, Leonid Aslanov, Yury Fedorov, Anatoly Galashin, Alexander Kamyshny

*Corresponding author for this work

Research output: Contribution to conferencePaperpeer-review

1 Scopus citations

Abstract

This work attempts to compare the SERS spectra of 2,2′-bipyridine on colloidal silver and a model photoemulsion-gelatin-stabilized AgBr sol. X-ray analysis, NMR, and quantum mechanical calculations reveal that the molecules of 2,2′-bipyridine exhibit planar trans-conformation. At the same time, 2,2′-bipyridine in cis-conformation readily forms the chelate complexes with different metals. Photophysical properties of 2,2′-bipyridine are studied in detail, and the analysis of vibrational spectra with assignment of the normal modes is also performed.

Original languageEnglish
Pages276-278
Number of pages3
StatePublished - 1995
Externally publishedYes
EventProceedings of the 1995 IS&T's 48th Annual Conference - Washington, DC, USA
Duration: 7 May 199511 May 1995

Conference

ConferenceProceedings of the 1995 IS&T's 48th Annual Conference
CityWashington, DC, USA
Period7/05/9511/05/95

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