Surface Geometry Effects on Adsorption-Desorption Hysteresis, Latent Adsorption and Adsorption-Probability Plots

Alon Seri-Levy; David Avnir

doi:10.1016/S0167-2991(08)63536-3

Surface Geometry Effects on Adsorption-Desorption Hysteresis, Latent Adsorption and Adsorption-Probability Plots

Alon Seri-Levy
, David Avnir

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

We perform molecular-level two-dimensional Monte-Carlo simulations of adsorption/desorption processes in order to investigate the effects that surface geometric irregularity has on these processes. The degree of surface irregularity is gradually changed by taking various profiles, starting from a straight line and ending in a microporous line. We correlate geometry to the appearance of adsorption-desorption hysteresis and to the evolution of latent adsorption (trapped, unadsorbed molecules).

Original language	English
Pages (from-to)	365-372
Number of pages	8
Journal	Studies in Surface Science and Catalysis
Volume	80
Issue number	C
DOIs	https://doi.org/10.1016/S0167-2991(08)63536-3
State	Published - 1 Jan 1993

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N2 - We perform molecular-level two-dimensional Monte-Carlo simulations of adsorption/desorption processes in order to investigate the effects that surface geometric irregularity has on these processes. The degree of surface irregularity is gradually changed by taking various profiles, starting from a straight line and ending in a microporous line. We correlate geometry to the appearance of adsorption-desorption hysteresis and to the evolution of latent adsorption (trapped, unadsorbed molecules).

AB - We perform molecular-level two-dimensional Monte-Carlo simulations of adsorption/desorption processes in order to investigate the effects that surface geometric irregularity has on these processes. The degree of surface irregularity is gradually changed by taking various profiles, starting from a straight line and ending in a microporous line. We correlate geometry to the appearance of adsorption-desorption hysteresis and to the evolution of latent adsorption (trapped, unadsorbed molecules).

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Surface Geometry Effects on Adsorption-Desorption Hysteresis, Latent Adsorption and Adsorption-Probability Plots

Abstract

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