Surprisal analysis derived from a variational principle for mechanical systems

N. Z. Tishby*, R. D. Levine

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

6 Scopus citations

Abstract

The expansion of the surprisal in one or a few observables is derived from a variational (action) principle for hamiltonian systems. Whenever phenomenological sum rules exist or "slow" variables can be identified on physical grounds, the variational approximation will be accurate and a hamiltonian-like formalism for the description of the collision in terms of a few variables is sufficient.

Original languageEnglish
Pages (from-to)310-314
Number of pages5
JournalChemical Physics Letters
Volume98
Issue number4
DOIs
StatePublished - 1 Jul 1983

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