Abstract
The expansion of the surprisal in one or a few observables is derived from a variational (action) principle for hamiltonian systems. Whenever phenomenological sum rules exist or "slow" variables can be identified on physical grounds, the variational approximation will be accurate and a hamiltonian-like formalism for the description of the collision in terms of a few variables is sufficient.
Original language | English |
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Pages (from-to) | 310-314 |
Number of pages | 5 |
Journal | Chemical Physics Letters |
Volume | 98 |
Issue number | 4 |
DOIs | |
State | Published - 1 Jul 1983 |