Surprisal analysis of diffusion processes

Rajendran Saravanan*, R. D. Levine

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

1 Scopus citations

Abstract

We report a preliminary step in the application of information theory motivated surprisal analysis to irreversible processes but having linear equations of motion. Here we aim to describe the dynamics of varied Smoluchowski diffusion processes. In surprisal analysis, the probability density over the sample space is written as an exponential function of linear combination of observables that pose as constraints to the density evolution. The coefficients of this expansion can be interpreted as Lagrange multipliers that arise in the maximum entropy formalism. Known solutions of diffusion processes can be reproduced exactly using such a description. An exponent that is a linear combination of observables can also provide a close approximation for the dominant behavior of the solution of some other interesting examples for which there are no known exact results.

Original languageEnglish
Article number111450
JournalChemical Physics
Volume556
DOIs
StatePublished - 1 Apr 2022

Bibliographical note

Publisher Copyright:
© 2022 Elsevier B.V.

Keywords

  • Classical dissipation
  • Maximum entropy formalism
  • Reaction-diffusion systems
  • Smoluchowski equation
  • Surprisal analysis

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