Synthesis and Characterization of the Linear Trinuclear Complexes [M 3II(O2CCH3)6(biphme)2], M = Mn, Fe

R. Lynn Rardin; Avi Bino; Peter Poganiuch; William B. Tolman; Shuncheng Liu; Stephen J. Lippard

doi:10.1002/anie.199008121

Synthesis and Characterization of the Linear Trinuclear Complexes [M 3II(O₂CCH₃)₆(biphme)₂], M = Mn, Fe

R. Lynn Rardin, Avi Bino, Peter Poganiuch, William B. Tolman, Shuncheng Liu, Stephen J. Lippard^*

^*Corresponding author for this work

Institute of Chemistry

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Abstract

A Mn₃ chain bridged by four bidentate and two monodentate carboxylate ligands characterizes the Mn^II title complex 1. Unique features are the monodentate acetate bridges, which have a “dangling” oxygen atom that influences the molecular structure through weak interactions with the terminal Mn atoms. (Figure Presented.)

Original language	English
Pages (from-to)	812-814
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	29
Issue number	7
DOIs	https://doi.org/10.1002/anie.199008121
State	Published - Jul 1990

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title = "Synthesis and Characterization of the Linear Trinuclear Complexes [M 3II(O2CCH3)6(biphme)2], M = Mn, Fe",

abstract = "A Mn3 chain bridged by four bidentate and two monodentate carboxylate ligands characterizes the MnII title complex 1. Unique features are the monodentate acetate bridges, which have a “dangling” oxygen atom that influences the molecular structure through weak interactions with the terminal Mn atoms. (Figure Presented.)",

author = "Rardin, {R. Lynn} and Avi Bino and Peter Poganiuch and Tolman, {William B.} and Shuncheng Liu and Lippard, {Stephen J.}",

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AU - Rardin, R. Lynn

AU - Bino, Avi

AU - Poganiuch, Peter

AU - Tolman, William B.

AU - Liu, Shuncheng

AU - Lippard, Stephen J.

PY - 1990/7

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N2 - A Mn3 chain bridged by four bidentate and two monodentate carboxylate ligands characterizes the MnII title complex 1. Unique features are the monodentate acetate bridges, which have a “dangling” oxygen atom that influences the molecular structure through weak interactions with the terminal Mn atoms. (Figure Presented.)

AB - A Mn3 chain bridged by four bidentate and two monodentate carboxylate ligands characterizes the MnII title complex 1. Unique features are the monodentate acetate bridges, which have a “dangling” oxygen atom that influences the molecular structure through weak interactions with the terminal Mn atoms. (Figure Presented.)

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Synthesis and Characterization of the Linear Trinuclear Complexes [M 3II(O₂CCH₃)₆(biphme)₂], M = Mn, Fe

Abstract

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