Synthesis and crystal structure of triphenyltin and lead complexes with organic peroxides

Alexander G. Medvedev; Mikhail Yu Sharipov; Dmitry A. Grishanov; Artur V. Eshtukov; Andrei V. Churakov; Ivan A. Buldashov; Pavel A. Egorov; Ovadia Lev; Petr V. Prikhodchenko

doi:10.1016/j.mencom.2022.01.018

Synthesis and crystal structure of triphenyltin and lead complexes with organic peroxides

Alexander G. Medvedev, Mikhail Yu Sharipov, Dmitry A. Grishanov, Artur V. Eshtukov, Andrei V. Churakov, Ivan A. Buldashov, Pavel A. Egorov, Ovadia Lev, Petr V. Prikhodchenko^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Crystalline triphenyltin cumyl and tert-butyl peroxides (Ph₃SnOOCMe₂Ph and Ph₃SnOOBu^t, respectively) and triphenyllead cumyl peroxide (Ph₃PbOOCMe₂Ph) were synthesized and characterized by single crystal and powder X-ray diffraction, NMR, FTIR and Raman spectroscopies, TG and DSC analysis. The formation of triphenyltin tert-butyl peroxide in benzene in the presence of a base was proved by ¹¹⁹Sn, ¹³C and ¹H NMR spectroscopy. To the best of our knowledge, the obtained complexes are the first structurally characterized coordination compounds of tin and lead with organic peroxides.

Original language	English
Pages (from-to)	57-59
Number of pages	3
Journal	Mendeleev Communications
Volume	32
Issue number	1
DOIs	https://doi.org/10.1016/j.mencom.2022.01.018
State	Published - 1 Jan 2022

Bibliographical note

Funding Information:
This work was supported by the Russian Science Foundation (grant no. 19-73-10208, synthesis of complexes 1 and 2 and characterization of complexes 1–3). X-ray diffraction study was performed using the equipment of the JRC PMR IGIC RAS within the framework of the State Assignment on Fundamental Research to the N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences. D.A.G. thanks the Council for Grants of the President of the Russian Federation (grant no. MK-4450.2021.1.3, synthesis of compound 3). O.L. thanks the Israel Science Foundation (grant no. 1215/19).

Publisher Copyright:
© 2022

Keywords

Coordination peroxo compounds
Hydrogen peroxide
Lead
Organic hydroperoxides
Peroxo complexes
Tin

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title = "Synthesis and crystal structure of triphenyltin and lead complexes with organic peroxides",

abstract = "Crystalline triphenyltin cumyl and tert-butyl peroxides (Ph3SnOOCMe2Ph and Ph3SnOOBut, respectively) and triphenyllead cumyl peroxide (Ph3PbOOCMe2Ph) were synthesized and characterized by single crystal and powder X-ray diffraction, NMR, FTIR and Raman spectroscopies, TG and DSC analysis. The formation of triphenyltin tert-butyl peroxide in benzene in the presence of a base was proved by 119Sn, 13C and 1H NMR spectroscopy. To the best of our knowledge, the obtained complexes are the first structurally characterized coordination compounds of tin and lead with organic peroxides.",

keywords = "Coordination peroxo compounds, Hydrogen peroxide, Lead, Organic hydroperoxides, Peroxo complexes, Tin",

author = "Medvedev, {Alexander G.} and Sharipov, {Mikhail Yu} and Grishanov, {Dmitry A.} and Eshtukov, {Artur V.} and Churakov, {Andrei V.} and Buldashov, {Ivan A.} and Egorov, {Pavel A.} and Ovadia Lev and Prikhodchenko, {Petr V.}",

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doi = "10.1016/j.mencom.2022.01.018",

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T1 - Synthesis and crystal structure of triphenyltin and lead complexes with organic peroxides

AU - Medvedev, Alexander G.

AU - Sharipov, Mikhail Yu

AU - Grishanov, Dmitry A.

AU - Eshtukov, Artur V.

AU - Churakov, Andrei V.

AU - Buldashov, Ivan A.

AU - Egorov, Pavel A.

AU - Lev, Ovadia

AU - Prikhodchenko, Petr V.

PY - 2022/1/1

Y1 - 2022/1/1

N2 - Crystalline triphenyltin cumyl and tert-butyl peroxides (Ph3SnOOCMe2Ph and Ph3SnOOBut, respectively) and triphenyllead cumyl peroxide (Ph3PbOOCMe2Ph) were synthesized and characterized by single crystal and powder X-ray diffraction, NMR, FTIR and Raman spectroscopies, TG and DSC analysis. The formation of triphenyltin tert-butyl peroxide in benzene in the presence of a base was proved by 119Sn, 13C and 1H NMR spectroscopy. To the best of our knowledge, the obtained complexes are the first structurally characterized coordination compounds of tin and lead with organic peroxides.

AB - Crystalline triphenyltin cumyl and tert-butyl peroxides (Ph3SnOOCMe2Ph and Ph3SnOOBut, respectively) and triphenyllead cumyl peroxide (Ph3PbOOCMe2Ph) were synthesized and characterized by single crystal and powder X-ray diffraction, NMR, FTIR and Raman spectroscopies, TG and DSC analysis. The formation of triphenyltin tert-butyl peroxide in benzene in the presence of a base was proved by 119Sn, 13C and 1H NMR spectroscopy. To the best of our knowledge, the obtained complexes are the first structurally characterized coordination compounds of tin and lead with organic peroxides.

KW - Coordination peroxo compounds

KW - Hydrogen peroxide

KW - Lead

KW - Organic hydroperoxides

KW - Peroxo complexes

KW - Tin

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SN - 0959-9436

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JO - Mendeleev Communications

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ER -

Synthesis and crystal structure of triphenyltin and lead complexes with organic peroxides

Abstract

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Keywords

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