Synthesis and reactions of large-ring spirodienone calixarene derivatives

Flavio Grynszpan; Oleg Aleksiuk; Silvio E. Biali

doi:10.1351/pac199668061249

Synthesis and reactions of large-ring spirodienone calixarene derivatives

Flavio Grynszpan, Oleg Aleksiuk, Silvio E. Biali^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

The isomerism of the polyspirodienone derivatives of the large-ring p-tert-butylcalix[n]arenes (n=5,6,8) is analyzed. Mono- and polyspirodienone calix[n]arene derivatives were prepared by mild oxidation of the respective calix[n]arenes and the obtained products were characterized. Reactions of the monospirodienone derivatives with hydrazines and their rearrangements to xanthenocalixarenes are described.

Original language	English
Pages (from-to)	1249-1254
Number of pages	6
Journal	Pure and Applied Chemistry
Volume	68
Issue number	6
DOIs	https://doi.org/10.1351/pac199668061249
State	Published - Jun 1996

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abstract = "The isomerism of the polyspirodienone derivatives of the large-ring p-tert-butylcalix[n]arenes (n=5,6,8) is analyzed. Mono- and polyspirodienone calix[n]arene derivatives were prepared by mild oxidation of the respective calix[n]arenes and the obtained products were characterized. Reactions of the monospirodienone derivatives with hydrazines and their rearrangements to xanthenocalixarenes are described.",

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AU - Biali, Silvio E.

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AB - The isomerism of the polyspirodienone derivatives of the large-ring p-tert-butylcalix[n]arenes (n=5,6,8) is analyzed. Mono- and polyspirodienone calix[n]arene derivatives were prepared by mild oxidation of the respective calix[n]arenes and the obtained products were characterized. Reactions of the monospirodienone derivatives with hydrazines and their rearrangements to xanthenocalixarenes are described.

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Synthesis and reactions of large-ring spirodienone calixarene derivatives

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