Synthesis and selectivity of sym-hydroxydibenzo-14crown-4 ionophores for protons, alkali metal cations, and alkaline earth cations in polymeric membranes

Uriel Olsher; Felix Frolow; Gil Shoham; Elzbieta Luboch; Zong Yuan Yu; Richard A. Bartsch

doi:10.1007/BF01041256

Synthesis and selectivity of sym-hydroxydibenzo-14crown-4 ionophores for protons, alkali metal cations, and alkaline earth cations in polymeric membranes

Uriel Olsher^*, Felix Frolow, Gil Shoham, Elzbieta Luboch, Zong Yuan Yu, Richard A. Bartsch

^*Corresponding author for this work

Institute of Chemistry

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12 Scopus citations

Abstract

Six derivatives of sym-hydroxydibenzo-14-crown-4 have been prepared and incorporated into solvent-polymeric membranes. Responses of the membranes to protons, alkali metal cations, and alkaline earth cations have been determined. The preferred uptake of protons is attributed to proton complexation by stable crown ether alcohol and diol monohydrate species.

Original language	English
Pages (from-to)	125-135
Number of pages	11
Journal	Journal of Inclusion Phenomena and Molecular Recognition in Chemistry
Volume	9
Issue number	2
DOIs	https://doi.org/10.1007/BF01041256
State	Published - Sep 1990

Keywords

Crown ether alcohols and diols
alkali metal cations and alkaline earth cations
selectivity for protons
solvent-polymeric membranes

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10.1007/BF01041256

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title = "Synthesis and selectivity of sym-hydroxydibenzo-14crown-4 ionophores for protons, alkali metal cations, and alkaline earth cations in polymeric membranes",

abstract = "Six derivatives of sym-hydroxydibenzo-14-crown-4 have been prepared and incorporated into solvent-polymeric membranes. Responses of the membranes to protons, alkali metal cations, and alkaline earth cations have been determined. The preferred uptake of protons is attributed to proton complexation by stable crown ether alcohol and diol monohydrate species.",

keywords = "Crown ether alcohols and diols, alkali metal cations and alkaline earth cations, selectivity for protons, solvent-polymeric membranes",

author = "Uriel Olsher and Felix Frolow and Gil Shoham and Elzbieta Luboch and Yu, {Zong Yuan} and Bartsch, {Richard A.}",

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volume = "9",

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Synthesis and selectivity of sym-hydroxydibenzo-14crown-4 ionophores for protons, alkali metal cations, and alkaline earth cations in polymeric membranes. / Olsher, Uriel; Frolow, Felix; Shoham, Gil et al.
In: Journal of Inclusion Phenomena and Molecular Recognition in Chemistry, Vol. 9, No. 2, 09.1990, p. 125-135.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and selectivity of sym-hydroxydibenzo-14crown-4 ionophores for protons, alkali metal cations, and alkaline earth cations in polymeric membranes

AU - Olsher, Uriel

AU - Frolow, Felix

AU - Shoham, Gil

AU - Luboch, Elzbieta

AU - Yu, Zong Yuan

AU - Bartsch, Richard A.

PY - 1990/9

Y1 - 1990/9

N2 - Six derivatives of sym-hydroxydibenzo-14-crown-4 have been prepared and incorporated into solvent-polymeric membranes. Responses of the membranes to protons, alkali metal cations, and alkaline earth cations have been determined. The preferred uptake of protons is attributed to proton complexation by stable crown ether alcohol and diol monohydrate species.

AB - Six derivatives of sym-hydroxydibenzo-14-crown-4 have been prepared and incorporated into solvent-polymeric membranes. Responses of the membranes to protons, alkali metal cations, and alkaline earth cations have been determined. The preferred uptake of protons is attributed to proton complexation by stable crown ether alcohol and diol monohydrate species.

KW - Crown ether alcohols and diols

KW - alkali metal cations and alkaline earth cations

KW - selectivity for protons

KW - solvent-polymeric membranes

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SN - 0923-0750

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JO - Journal of Inclusion Phenomena and Molecular Recognition in Chemistry

JF - Journal of Inclusion Phenomena and Molecular Recognition in Chemistry

IS - 2

ER -

Synthesis and selectivity of sym-hydroxydibenzo-14crown-4 ionophores for protons, alkali metal cations, and alkaline earth cations in polymeric membranes

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Keywords

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