Synthesis of 3-hydroxy-1-alkenylboronates via phosphine stabilized borylzirconacyclopropenes

Abed Al Aziz Al Quntar; Alina Botvinik; Abraham Rubinstein; Morris Srebnik

doi:10.1039/b811287h

Synthesis of 3-hydroxy-1-alkenylboronates via phosphine stabilized borylzirconacyclopropenes

Abed Al Aziz Al Quntar, Alina Botvinik, Abraham Rubinstein, Morris Srebnik^*

^*Corresponding author for this work

School of Pharmacy

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Zirconacyclopropenylboronates can be stabilized to dimerization by complexation with tributylphosphine; the phosphine stabilized zirconacycle boronates react with aliphatic and aromatic ketones and aldehydes at C2 of the triple bond to give the previously unknown 3-hydroxyvinylboronates in 61-80% isolated yields.

Original language	English
Pages (from-to)	5589-5591
Number of pages	3
Journal	Chemical Communications
Issue number	43
DOIs	https://doi.org/10.1039/b811287h
State	Published - 2008

Access to Document

10.1039/b811287h

Cite this

@article{9cfee073d9714e22b3fcc8a9f44601b1,

title = "Synthesis of 3-hydroxy-1-alkenylboronates via phosphine stabilized borylzirconacyclopropenes",

abstract = "Zirconacyclopropenylboronates can be stabilized to dimerization by complexation with tributylphosphine; the phosphine stabilized zirconacycle boronates react with aliphatic and aromatic ketones and aldehydes at C2 of the triple bond to give the previously unknown 3-hydroxyvinylboronates in 61-80% isolated yields.",

author = "{Al Quntar}, {Abed Al Aziz} and Alina Botvinik and Abraham Rubinstein and Morris Srebnik",

year = "2008",

doi = "10.1039/b811287h",

language = "אנגלית",

pages = "5589--5591",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "43",

}

TY - JOUR

T1 - Synthesis of 3-hydroxy-1-alkenylboronates via phosphine stabilized borylzirconacyclopropenes

AU - Al Quntar, Abed Al Aziz

AU - Botvinik, Alina

AU - Rubinstein, Abraham

AU - Srebnik, Morris

PY - 2008

Y1 - 2008

N2 - Zirconacyclopropenylboronates can be stabilized to dimerization by complexation with tributylphosphine; the phosphine stabilized zirconacycle boronates react with aliphatic and aromatic ketones and aldehydes at C2 of the triple bond to give the previously unknown 3-hydroxyvinylboronates in 61-80% isolated yields.

AB - Zirconacyclopropenylboronates can be stabilized to dimerization by complexation with tributylphosphine; the phosphine stabilized zirconacycle boronates react with aliphatic and aromatic ketones and aldehydes at C2 of the triple bond to give the previously unknown 3-hydroxyvinylboronates in 61-80% isolated yields.

UR - http://www.scopus.com/inward/record.url?scp=55849087318&partnerID=8YFLogxK

U2 - 10.1039/b811287h

DO - 10.1039/b811287h

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

C2 - 18997961

AN - SCOPUS:55849087318

SN - 1359-7345

SP - 5589

EP - 5591

JO - Chemical Communications

JF - Chemical Communications

IS - 43

ER -

Synthesis of 3-hydroxy-1-alkenylboronates via phosphine stabilized borylzirconacyclopropenes

Abstract

Access to Document

Other files and links

Fingerprint

Cite this