Synthesis of Poly-5-vinylindole Derivatives

Ben Zion Weiner; Albert Zilkha

doi:10.1080/00222337708066571

Synthesis of Poly-5-vinylindole Derivatives

Ben Zion Weiner, Albert Zilkha

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

5-Vinyl-N-benzylindoline and 5-vinyl-N-benzylindole were synthesized starting from the corresponding 5-formyl derivative, by utilizing the Wittig or Wittig-Horner reactions. The monomers were polymerized by free-radical (AIBN) and anionic (BuLi) catalysts. Poly-5-vinyl-N-benzylindole was converted through suitable reactions to the tryptamine and indole acetic acid derivatives. Poly-5-vinyl-N-benzyl-tryptophane was synthesized by malonic ester synthesis by utilizing the condensation of poly-5-vinyl-N-benzylgramine and diethyl formamidomalonate.

Original language	English
Pages (from-to)	751-765
Number of pages	15
Journal	Journal of Macromolecular Science: Part A - Chemistry
Volume	11
Issue number	4
DOIs	https://doi.org/10.1080/00222337708066571
State	Published - 1 Apr 1977

Access to Document

10.1080/00222337708066571

Cite this

@article{eeea462ce5f1421f9e633538bbbae94d,

title = "Synthesis of Poly-5-vinylindole Derivatives",

abstract = "5-Vinyl-N-benzylindoline and 5-vinyl-N-benzylindole were synthesized starting from the corresponding 5-formyl derivative, by utilizing the Wittig or Wittig-Horner reactions. The monomers were polymerized by free-radical (AIBN) and anionic (BuLi) catalysts. Poly-5-vinyl-N-benzylindole was converted through suitable reactions to the tryptamine and indole acetic acid derivatives. Poly-5-vinyl-N-benzyl-tryptophane was synthesized by malonic ester synthesis by utilizing the condensation of poly-5-vinyl-N-benzylgramine and diethyl formamidomalonate.",

author = "Weiner, {Ben Zion} and Albert Zilkha",

year = "1977",

month = apr,

day = "1",

doi = "10.1080/00222337708066571",

language = "אנגלית",

volume = "11",

pages = "751--765",

journal = "Journal of Macromolecular Science: Part A - Chemistry",

issn = "0022-233X",

publisher = "Taylor and Francis Ltd.",

number = "4",

}

TY - JOUR

T1 - Synthesis of Poly-5-vinylindole Derivatives

AU - Weiner, Ben Zion

AU - Zilkha, Albert

PY - 1977/4/1

Y1 - 1977/4/1

N2 - 5-Vinyl-N-benzylindoline and 5-vinyl-N-benzylindole were synthesized starting from the corresponding 5-formyl derivative, by utilizing the Wittig or Wittig-Horner reactions. The monomers were polymerized by free-radical (AIBN) and anionic (BuLi) catalysts. Poly-5-vinyl-N-benzylindole was converted through suitable reactions to the tryptamine and indole acetic acid derivatives. Poly-5-vinyl-N-benzyl-tryptophane was synthesized by malonic ester synthesis by utilizing the condensation of poly-5-vinyl-N-benzylgramine and diethyl formamidomalonate.

AB - 5-Vinyl-N-benzylindoline and 5-vinyl-N-benzylindole were synthesized starting from the corresponding 5-formyl derivative, by utilizing the Wittig or Wittig-Horner reactions. The monomers were polymerized by free-radical (AIBN) and anionic (BuLi) catalysts. Poly-5-vinyl-N-benzylindole was converted through suitable reactions to the tryptamine and indole acetic acid derivatives. Poly-5-vinyl-N-benzyl-tryptophane was synthesized by malonic ester synthesis by utilizing the condensation of poly-5-vinyl-N-benzylgramine and diethyl formamidomalonate.

UR - http://www.scopus.com/inward/record.url?scp=84953999567&partnerID=8YFLogxK

U2 - 10.1080/00222337708066571

DO - 10.1080/00222337708066571

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

AN - SCOPUS:84953999567

SN - 0022-233X

VL - 11

SP - 751

EP - 765

JO - Journal of Macromolecular Science: Part A - Chemistry

JF - Journal of Macromolecular Science: Part A - Chemistry

IS - 4

ER -

Synthesis of Poly-5-vinylindole Derivatives

Abstract

Access to Document

Other files and links

Fingerprint

Cite this