Synthesis of Quaternary Ammonium Fluoride Salts by a Solid-Liquid Halogen Exchange Process in Protic Solvents

Salman Dermeik; Yoel Sasson

doi:10.1021/jo00281a024

Synthesis of Quaternary Ammonium Fluoride Salts by a Solid-Liquid Halogen Exchange Process in Protic Solvents

Salman Dermeik
, Yoel Sasson^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

Both hydrophilic and lipophilic quaternary ammonium fluoride compounds are prepared by direct exchange of the corresponding halides with solid potassium fluoride containing an optimized amount of water (4.0 mol %). The procedure is most effective when methanol is applied as a solvent. A variety of quaternary ammonium fluorides were prepared in 75-97% yield.

Original language	English
Pages (from-to)	4827-4829
Number of pages	3
Journal	Journal of Organic Chemistry
Volume	54
Issue number	20
DOIs	https://doi.org/10.1021/jo00281a024
State	Published - 1 Sep 1989

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title = "Synthesis of Quaternary Ammonium Fluoride Salts by a Solid-Liquid Halogen Exchange Process in Protic Solvents",

abstract = "Both hydrophilic and lipophilic quaternary ammonium fluoride compounds are prepared by direct exchange of the corresponding halides with solid potassium fluoride containing an optimized amount of water (4.0 mol \%). The procedure is most effective when methanol is applied as a solvent. A variety of quaternary ammonium fluorides were prepared in 75-97\% yield.",

author = "Salman Dermeik and Yoel Sasson",

year = "1989",

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doi = "10.1021/jo00281a024",

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AU - Sasson, Yoel

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Y1 - 1989/9/1

N2 - Both hydrophilic and lipophilic quaternary ammonium fluoride compounds are prepared by direct exchange of the corresponding halides with solid potassium fluoride containing an optimized amount of water (4.0 mol %). The procedure is most effective when methanol is applied as a solvent. A variety of quaternary ammonium fluorides were prepared in 75-97% yield.

AB - Both hydrophilic and lipophilic quaternary ammonium fluoride compounds are prepared by direct exchange of the corresponding halides with solid potassium fluoride containing an optimized amount of water (4.0 mol %). The procedure is most effective when methanol is applied as a solvent. A variety of quaternary ammonium fluorides were prepared in 75-97% yield.

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JO - Journal of Organic Chemistry

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IS - 20

ER -

Synthesis of Quaternary Ammonium Fluoride Salts by a Solid-Liquid Halogen Exchange Process in Protic Solvents

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