Synthesis of water soluble PbSe quantum dots

Lioz Etgar*, Efrat Lifshitz, Rina Tannenbaum

*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

1 Scopus citations

Abstract

Water-soluble PbSe semiconductor quantum dots (QDs) with near-infrared absorption of 1100-2520 nm (corresponding to a diameter of 3-13 nm) were synthesized using 2-aminoethanthiol. The oleic acid stabilizing ligands used in the traditional synthesis of PbSe were exchanged with the 2-aminoethanethiol (AET) ligands, which promoted the solubilization of the QDs in an aqueous medium. This occurred due to the attraction of the surrounding water molecules to the exposed amino-group, thus allowing the particles to reside in the water environment. The water-soluble PbSe QDs have very narrow size distribution (σ ≈ 4.5-5.5%). Transmission electron microscopy (TEM), spectrophotometric measurements, and Fourier transform infrared (FTIR) spectroscopy indicate that the morphology, size, size distribution and chemical composition of the PbSe QDs remained unchanged during the transfer to an aqueous medium. In conclusion, the ability to synthesize water soluble PbSe QDs with stable properties and uniform size distribution will allow them to have substantial advantages for biological applications such as biosensors and drug delivery.

Original languageAmerican English
Title of host publicationQuantum Dots
Subtitle of host publicationGrowth, Behavior and Applications
Pages172-177
Number of pages6
StatePublished - 2007
Externally publishedYes
Event2006 MRS Fall Meeting - Boston, MA, United States
Duration: 27 Nov 20061 Dec 2006

Publication series

NameMaterials Research Society Symposium Proceedings
Volume959
ISSN (Print)0272-9172

Conference

Conference2006 MRS Fall Meeting
Country/TerritoryUnited States
CityBoston, MA
Period27/11/061/12/06

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