Tandem pinacol coupling-rearrangement of aromatic aldehydes with hydrogen catalyzed by a combination of a platinum complex and a polyoxometalate

Olena Branytska; Linda J.W. Shimon; Ronny Neumann

doi:10.1039/b710100g

Tandem pinacol coupling-rearrangement of aromatic aldehydes with hydrogen catalyzed by a combination of a platinum complex and a polyoxometalate

Olena Branytska
, Linda J.W. Shimon
, Ronny Neumann^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

Together with a strongly oxidizing polyoxometalate, H₅PV ₂Mo₁₀O₄₀, Pt^II(N-(2,6- diisopropylphenyl)pyrazin-2-ylmethanimine)Cl₂ forms a combined catalyst that was active in the tandem pinacol coupling-rearrangement of aryl aldehydes to give mostly the corresponding diarylacetaldehyde in high yields using molecular hydrogen as the reducing agent.

Original language	English
Pages (from-to)	3957-3959
Number of pages	3
Journal	Chemical Communications
Issue number	38
DOIs	https://doi.org/10.1039/b710100g
State	Published - 2007
Externally published	Yes

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title = "Tandem pinacol coupling-rearrangement of aromatic aldehydes with hydrogen catalyzed by a combination of a platinum complex and a polyoxometalate",

abstract = "Together with a strongly oxidizing polyoxometalate, H5PV 2Mo10O40, PtII(N-(2,6- diisopropylphenyl)pyrazin-2-ylmethanimine)Cl2 forms a combined catalyst that was active in the tandem pinacol coupling-rearrangement of aryl aldehydes to give mostly the corresponding diarylacetaldehyde in high yields using molecular hydrogen as the reducing agent.",

author = "Olena Branytska and Shimon, \{Linda J.W.\} and Ronny Neumann",

year = "2007",

doi = "10.1039/b710100g",

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publisher = "Royal Society of Chemistry",

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AU - Branytska, Olena

AU - Shimon, Linda J.W.

AU - Neumann, Ronny

PY - 2007

Y1 - 2007

N2 - Together with a strongly oxidizing polyoxometalate, H5PV 2Mo10O40, PtII(N-(2,6- diisopropylphenyl)pyrazin-2-ylmethanimine)Cl2 forms a combined catalyst that was active in the tandem pinacol coupling-rearrangement of aryl aldehydes to give mostly the corresponding diarylacetaldehyde in high yields using molecular hydrogen as the reducing agent.

AB - Together with a strongly oxidizing polyoxometalate, H5PV 2Mo10O40, PtII(N-(2,6- diisopropylphenyl)pyrazin-2-ylmethanimine)Cl2 forms a combined catalyst that was active in the tandem pinacol coupling-rearrangement of aryl aldehydes to give mostly the corresponding diarylacetaldehyde in high yields using molecular hydrogen as the reducing agent.

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DO - 10.1039/b710100g

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AN - SCOPUS:38849122146

SN - 1359-7345

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JO - Chemical Communications

JF - Chemical Communications

IS - 38

ER -

Tandem pinacol coupling-rearrangement of aromatic aldehydes with hydrogen catalyzed by a combination of a platinum complex and a polyoxometalate

Abstract

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