TY - JOUR
T1 - Tetrachloro-phosphonium salts of hexachloro antimonate and niobate and their solvates. Preparation and structure by vibrational spectroscopy and x-ray crystallography
AU - Shamir, Jacob
AU - Luski, Shalom
AU - Bino, Avi
AU - Cohen, Shmuel
AU - Gibson, Dan
PY - 1985/10/15
Y1 - 1985/10/15
N2 - Four ionic compounds were isolated and identified: [PCl4] [SbCl6],1; [PCl4] [SbCl6]· 1 2POCl3,2; [PCl4] [NbCl6], 3; and [PCl4] [NbCl6]·SOCl2, 4. Vibrational spectra were obtained for all these substances and compound 2 was also characterized by X-ray crystallography. This compound crystallizes in the tetragonal space group P42/mbc with a = 14.658(2) Å, c = 14.915(2) Å and Z = 8. The structure was refined by least-squares methods using 1154 reflections to a conventional R factor of 2.8%.
AB - Four ionic compounds were isolated and identified: [PCl4] [SbCl6],1; [PCl4] [SbCl6]· 1 2POCl3,2; [PCl4] [NbCl6], 3; and [PCl4] [NbCl6]·SOCl2, 4. Vibrational spectra were obtained for all these substances and compound 2 was also characterized by X-ray crystallography. This compound crystallizes in the tetragonal space group P42/mbc with a = 14.658(2) Å, c = 14.915(2) Å and Z = 8. The structure was refined by least-squares methods using 1154 reflections to a conventional R factor of 2.8%.
UR - http://www.scopus.com/inward/record.url?scp=46549090588&partnerID=8YFLogxK
U2 - 10.1016/S0020-1693(00)86422-1
DO - 10.1016/S0020-1693(00)86422-1
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AN - SCOPUS:46549090588
SN - 0020-1693
VL - 104
SP - 91
EP - 97
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
IS - 2
ER -