The analysis of intensity fluctuations for a fully resolved spectrum: Pyrazine

J. Kommandeur; W. L. Meerts; Y. M. Engel; R. D. Levine

doi:10.1063/1.454379

The analysis of intensity fluctuations for a fully resolved spectrum: Pyrazine

J. Kommandeur^*, W. L. Meerts, Y. M. Engel, R. D. Levine

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Intensity fluctuations in the recently published fluorescence excitation spectrum of pyrazine in the ¹B_3u ← ¹A _g O₀⁰ band are analyzed. A numerical study of a model Hamiltonian of a bright state coupled to a manifold of dark states is performed as an aid to the interpretation of the results. The distribution of fluctuations in the intensities computed for the model Hamiltonian is near to that expected in the chaotic limit.

Original language	English
Pages (from-to)	6810-6813
Number of pages	4
Journal	The Journal of Chemical Physics
Volume	88
Issue number	11
DOIs	https://doi.org/10.1063/1.454379
State	Published - 1988

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title = "The analysis of intensity fluctuations for a fully resolved spectrum: Pyrazine",

abstract = "Intensity fluctuations in the recently published fluorescence excitation spectrum of pyrazine in the 1B3u ← 1A g O00 band are analyzed. A numerical study of a model Hamiltonian of a bright state coupled to a manifold of dark states is performed as an aid to the interpretation of the results. The distribution of fluctuations in the intensities computed for the model Hamiltonian is near to that expected in the chaotic limit.",

author = "J. Kommandeur and Meerts, {W. L.} and Engel, {Y. M.} and Levine, {R. D.}",

year = "1988",

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AU - Engel, Y. M.

AU - Levine, R. D.

PY - 1988

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AB - Intensity fluctuations in the recently published fluorescence excitation spectrum of pyrazine in the 1B3u ← 1A g O00 band are analyzed. A numerical study of a model Hamiltonian of a bright state coupled to a manifold of dark states is performed as an aid to the interpretation of the results. The distribution of fluctuations in the intensities computed for the model Hamiltonian is near to that expected in the chaotic limit.

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The analysis of intensity fluctuations for a fully resolved spectrum: Pyrazine

Abstract

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