TY - JOUR
T1 - The anion exchange of metal complexes-XI application of the constant ionic medium method to the mercury halide system
AU - Eliezer, I.
AU - Marcus, Y.
PY - 1963/11
Y1 - 1963/11
N2 - The applicability of the constant ionic medium method to the study of metal complex formation by exchange has been investigated, using the mercury(II) halide system as an illustration. The distribution of mercury(II) tracer has been measured between C molar (NaX + NaClO4) solution and (RX + RClO4) Dowex 1 resin, for C = 0·3, 0·5 and 3·0 M and X = Cl-, Br- and I-. The stability constants for the resin phase and for the 0·3 and 3 M solutions have been calculated. The general applicability of the method for anion exchange studies has been discussed.
AB - The applicability of the constant ionic medium method to the study of metal complex formation by exchange has been investigated, using the mercury(II) halide system as an illustration. The distribution of mercury(II) tracer has been measured between C molar (NaX + NaClO4) solution and (RX + RClO4) Dowex 1 resin, for C = 0·3, 0·5 and 3·0 M and X = Cl-, Br- and I-. The stability constants for the resin phase and for the 0·3 and 3 M solutions have been calculated. The general applicability of the method for anion exchange studies has been discussed.
UR - http://www.scopus.com/inward/record.url?scp=3543035592&partnerID=8YFLogxK
U2 - 10.1016/0022-1902(63)80418-2
DO - 10.1016/0022-1902(63)80418-2
M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???
AN - SCOPUS:3543035592
SN - 0022-1902
VL - 25
SP - 1465
EP - 1470
JO - Journal of Inorganic and Nuclear Chemistry
JF - Journal of Inorganic and Nuclear Chemistry
IS - 11
ER -