The anion exchange of metal complexes-XI application of the constant ionic medium method to the mercury halide system

I. Eliezer; Y. Marcus

doi:10.1016/0022-1902(63)80418-2

The anion exchange of metal complexes-XI application of the constant ionic medium method to the mercury halide system

I. Eliezer^*
, Y. Marcus

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

The applicability of the constant ionic medium method to the study of metal complex formation by exchange has been investigated, using the mercury(II) halide system as an illustration. The distribution of mercury(II) tracer has been measured between C molar (NaX + NaClO₄) solution and (RX + RClO₄) Dowex 1 resin, for C = 0·3, 0·5 and 3·0 M and X = Cl^-, Br^- and I^-. The stability constants for the resin phase and for the 0·3 and 3 M solutions have been calculated. The general applicability of the method for anion exchange studies has been discussed.

Original language	English
Pages (from-to)	1465-1470
Number of pages	6
Journal	Journal of Inorganic and Nuclear Chemistry
Volume	25
Issue number	11
DOIs	https://doi.org/10.1016/0022-1902(63)80418-2
State	Published - Nov 1963
Externally published	Yes

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title = "The anion exchange of metal complexes-XI application of the constant ionic medium method to the mercury halide system",

abstract = "The applicability of the constant ionic medium method to the study of metal complex formation by exchange has been investigated, using the mercury(II) halide system as an illustration. The distribution of mercury(II) tracer has been measured between C molar (NaX + NaClO4) solution and (RX + RClO4) Dowex 1 resin, for C = 0·3, 0·5 and 3·0 M and X = Cl-, Br- and I-. The stability constants for the resin phase and for the 0·3 and 3 M solutions have been calculated. The general applicability of the method for anion exchange studies has been discussed.",

author = "I. Eliezer and Y. Marcus",

year = "1963",

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doi = "10.1016/0022-1902(63)80418-2",

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AB - The applicability of the constant ionic medium method to the study of metal complex formation by exchange has been investigated, using the mercury(II) halide system as an illustration. The distribution of mercury(II) tracer has been measured between C molar (NaX + NaClO4) solution and (RX + RClO4) Dowex 1 resin, for C = 0·3, 0·5 and 3·0 M and X = Cl-, Br- and I-. The stability constants for the resin phase and for the 0·3 and 3 M solutions have been calculated. The general applicability of the method for anion exchange studies has been discussed.

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IS - 11

ER -

The anion exchange of metal complexes-XI application of the constant ionic medium method to the mercury halide system

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