The application of Fourier transform Raman spectroscopy to the analysis of poly(anhydride) homo- and co-polymers

A. M. Tudor; C. D. Melia; M. C. Davies; P. J. Hendra; S. Church; A. J. Domb; R. Langer

doi:10.1016/0584-8539(91)80224-7

The application of Fourier transform Raman spectroscopy to the analysis of poly(anhydride) homo- and co-polymers

A. M. Tudor
, C. D. Melia
, M. C. Davies^*
, P. J. Hendra
, S. Church
, A. J. Domb
, R. Langer

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

Fourier transform Raman spectroscopy was used to characterise a homologous series of aliphatic poly(anhydrides), poly[bis(p-carboxyphenoxy) alkane anhydrides] and a selection of co-polymers of sebacic/ [bis(p-carboxyphenoxy) propane anhydride] P(SA-CPP). The techniqe is compared to conventional infrared for characterisation work, highlighting the advantage of small sample requirement and minimal sample preparation necessary for acquisition of spectral information. It is possible to differentiate between aromatic and aliphatic anhydride bonding, and in conjunction with other diagnostic bands to monitor the change in individual monomer composition within a co-polymer mixture.

Original language	English
Pages (from-to)	1335-1343
Number of pages	9
Journal	Spectrochimica Acta - Part A Molecular Spectroscopy
Volume	47
Issue number	9-10
DOIs	https://doi.org/10.1016/0584-8539(91)80224-7
State	Published - 1991
Externally published	Yes

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10.1016/0584-8539(91)80224-7

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title = "The application of Fourier transform Raman spectroscopy to the analysis of poly(anhydride) homo- and co-polymers",

abstract = "Fourier transform Raman spectroscopy was used to characterise a homologous series of aliphatic poly(anhydrides), poly[bis(p-carboxyphenoxy) alkane anhydrides] and a selection of co-polymers of sebacic/ [bis(p-carboxyphenoxy) propane anhydride] P(SA-CPP). The techniqe is compared to conventional infrared for characterisation work, highlighting the advantage of small sample requirement and minimal sample preparation necessary for acquisition of spectral information. It is possible to differentiate between aromatic and aliphatic anhydride bonding, and in conjunction with other diagnostic bands to monitor the change in individual monomer composition within a co-polymer mixture.",

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year = "1991",

doi = "10.1016/0584-8539(91)80224-7",

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AU - Tudor, A. M.

AU - Melia, C. D.

AU - Davies, M. C.

AU - Hendra, P. J.

AU - Church, S.

AU - Domb, A. J.

AU - Langer, R.

PY - 1991

Y1 - 1991

N2 - Fourier transform Raman spectroscopy was used to characterise a homologous series of aliphatic poly(anhydrides), poly[bis(p-carboxyphenoxy) alkane anhydrides] and a selection of co-polymers of sebacic/ [bis(p-carboxyphenoxy) propane anhydride] P(SA-CPP). The techniqe is compared to conventional infrared for characterisation work, highlighting the advantage of small sample requirement and minimal sample preparation necessary for acquisition of spectral information. It is possible to differentiate between aromatic and aliphatic anhydride bonding, and in conjunction with other diagnostic bands to monitor the change in individual monomer composition within a co-polymer mixture.

AB - Fourier transform Raman spectroscopy was used to characterise a homologous series of aliphatic poly(anhydrides), poly[bis(p-carboxyphenoxy) alkane anhydrides] and a selection of co-polymers of sebacic/ [bis(p-carboxyphenoxy) propane anhydride] P(SA-CPP). The techniqe is compared to conventional infrared for characterisation work, highlighting the advantage of small sample requirement and minimal sample preparation necessary for acquisition of spectral information. It is possible to differentiate between aromatic and aliphatic anhydride bonding, and in conjunction with other diagnostic bands to monitor the change in individual monomer composition within a co-polymer mixture.

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The application of Fourier transform Raman spectroscopy to the analysis of poly(anhydride) homo- and co-polymers

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