TY - JOUR
T1 - The crystal and molecular structures of dichloro [N,O-(D,L)-diaminopropionic acid] platinum(II) and Dichloro [N,O-(L)-lysine] platinum(II) monohydrate
AU - Bino, Avi
AU - Cohen, Shmuel
AU - Altman, Janina
AU - Wilchek, Meir
PY - 1988/7/1
Y1 - 1988/7/1
N2 - K2PtCl4 reacts with L-lysine and with D,L-diaminiopropionic acid (Dap) forming the neutral complexes [PtCl2(N,O-Lys)]·H20 (1) and [PtCl2(N,O-Dap)], (2) respectively. Compound 1 is monoclinic, space group P21 with a = 11.262(3), b = 11.041(2), c = 9.690(2) Å, β = 102.07(5)°, V = 1178(1) Å3 and Z = 4. Compound 2 is monoclinic, space group P21/n with a = 8.777(1), b = 10.615(2), c = 7.947(1) Å, β = 94.98(3)°, V = 738(1) Å3 and Z = 4. In both compounds, the zwitterionic ligands form an N,O-five membered chelate with the platinum atom. Structures 1 and 2 were refined to R values of 3.3% and 6.3% respectively.
AB - K2PtCl4 reacts with L-lysine and with D,L-diaminiopropionic acid (Dap) forming the neutral complexes [PtCl2(N,O-Lys)]·H20 (1) and [PtCl2(N,O-Dap)], (2) respectively. Compound 1 is monoclinic, space group P21 with a = 11.262(3), b = 11.041(2), c = 9.690(2) Å, β = 102.07(5)°, V = 1178(1) Å3 and Z = 4. Compound 2 is monoclinic, space group P21/n with a = 8.777(1), b = 10.615(2), c = 7.947(1) Å, β = 94.98(3)°, V = 738(1) Å3 and Z = 4. In both compounds, the zwitterionic ligands form an N,O-five membered chelate with the platinum atom. Structures 1 and 2 were refined to R values of 3.3% and 6.3% respectively.
UR - https://www.scopus.com/pages/publications/0002796164
U2 - 10.1016/S0020-1693(00)80636-2
DO - 10.1016/S0020-1693(00)80636-2
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AN - SCOPUS:0002796164
SN - 0020-1693
VL - 147
SP - 99
EP - 102
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
IS - 1
ER -