The decomposition of chloroacetic acid in aqueous solutions by atomic hydrogen. II. Reaction mechanism in alkaline solutions

Joshua Jortner; Joseph Rabani

doi:10.1021/j100817a003

The decomposition of chloroacetic acid in aqueous solutions by atomic hydrogen. II. Reaction mechanism in alkaline solutions

Joshua Jortner^*, Joseph Rabani

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

The reactivity of atomic hydrogen in alkaline solutions of chloroacetic acid was investigated. The pH and concentration dependence yield kinetic evidence for the formation of H₂O^- in alkaline solutions: H + OH^-→ H₂O^- with k_H+OH- = 6 × 10⁵ l. mole^-1 sec.^-1. These results are correlated with radiation chemical data, and the nature of the H₂O^- radical is discussed.

Original language	English
Pages (from-to)	2081-2084
Number of pages	4
Journal	Journal of Physical Chemistry
Volume	66
Issue number	11
DOIs	https://doi.org/10.1021/j100817a003
State	Published - 1962

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title = "The decomposition of chloroacetic acid in aqueous solutions by atomic hydrogen. II. Reaction mechanism in alkaline solutions",

abstract = "The reactivity of atomic hydrogen in alkaline solutions of chloroacetic acid was investigated. The pH and concentration dependence yield kinetic evidence for the formation of H2O- in alkaline solutions: H + OH-→ H2O- with kH+OH- = 6 × 105 l. mole-1 sec.-1. These results are correlated with radiation chemical data, and the nature of the H2O- radical is discussed.",

author = "Joshua Jortner and Joseph Rabani",

year = "1962",

doi = "10.1021/j100817a003",

language = "אנגלית",

volume = "66",

pages = "2081--2084",

journal = "Journal of Physical Chemistry",

issn = "0022-3654",

publisher = "American Chemical Society",

number = "11",

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T1 - The decomposition of chloroacetic acid in aqueous solutions by atomic hydrogen. II. Reaction mechanism in alkaline solutions

AU - Jortner, Joshua

AU - Rabani, Joseph

PY - 1962

Y1 - 1962

N2 - The reactivity of atomic hydrogen in alkaline solutions of chloroacetic acid was investigated. The pH and concentration dependence yield kinetic evidence for the formation of H2O- in alkaline solutions: H + OH-→ H2O- with kH+OH- = 6 × 105 l. mole-1 sec.-1. These results are correlated with radiation chemical data, and the nature of the H2O- radical is discussed.

AB - The reactivity of atomic hydrogen in alkaline solutions of chloroacetic acid was investigated. The pH and concentration dependence yield kinetic evidence for the formation of H2O- in alkaline solutions: H + OH-→ H2O- with kH+OH- = 6 × 105 l. mole-1 sec.-1. These results are correlated with radiation chemical data, and the nature of the H2O- radical is discussed.

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DO - 10.1021/j100817a003

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AN - SCOPUS:0042944607

SN - 0022-3654

VL - 66

SP - 2081

EP - 2084

JO - Journal of Physical Chemistry

JF - Journal of Physical Chemistry

IS - 11

ER -

The decomposition of chloroacetic acid in aqueous solutions by atomic hydrogen. II. Reaction mechanism in alkaline solutions

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