The determination of the nephelauxetic effect in oxide glasses by Sn2+, Sb3+, Tl+, Pb2+ and Bi3+ ions

R. Reisfeld; L. Boehm

doi:10.1016/0022-3093(75)90051-4

The determination of the nephelauxetic effect in oxide glasses by Sn²⁺, Sb³⁺, Tl⁺, Pb²⁺ and Bi³⁺ ions

R. Reisfeld^*
, L. Boehm

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

The nephelauxetic parameter β was measured for Sn²⁺, Sb³⁺, Tl⁺, Pb²⁺ and Bi³⁺ incorporated in phosophate, borate and germanate glasses. β and Pauling electronegativity of glass-forming cations were correlated. It was found that the factors h and k obtained from the nephelauxetic effect are interrelated and both depend on the cation for which they were calculated.

Original language	English
Pages (from-to)	209-214
Number of pages	6
Journal	Journal of Non-Crystalline Solids
Volume	17
Issue number	2
DOIs	https://doi.org/10.1016/0022-3093(75)90051-4
State	Published - Mar 1975

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abstract = "The nephelauxetic parameter β was measured for Sn2+, Sb3+, Tl+, Pb2+ and Bi3+ incorporated in phosophate, borate and germanate glasses. β and Pauling electronegativity of glass-forming cations were correlated. It was found that the factors h and k obtained from the nephelauxetic effect are interrelated and both depend on the cation for which they were calculated.",

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AB - The nephelauxetic parameter β was measured for Sn2+, Sb3+, Tl+, Pb2+ and Bi3+ incorporated in phosophate, borate and germanate glasses. β and Pauling electronegativity of glass-forming cations were correlated. It was found that the factors h and k obtained from the nephelauxetic effect are interrelated and both depend on the cation for which they were calculated.

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The determination of the nephelauxetic effect in oxide glasses by Sn²⁺, Sb³⁺, Tl⁺, Pb²⁺ and Bi³⁺ ions

Abstract

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