The Diffusion of Divalent Europium into Single Crystals of Potassium Chloride

Renata Reisfeld*, A. Honigbaum

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

1 Scopus citations

Abstract

The diffusion of europium was studied in single crystals of potassium chloride by the spectrophotometric method. Measurements were carried out in the temperature range 418–550†C. The absorption spectra as well as the fluorescence spectra of crystals showed that europium diffused in its divalent state, being reduced by the crystal field of potassium chloride. The diffusion of europium can be represented by the equation D = 6.45. 10−2exp(‐29.400/RT). It is concluded that the activation energy consists of the sum of the jump energy of Eu2+ and of the enthalpy of solution of EuCl2 in KCl.

Original languageEnglish
Pages (from-to)53-59
Number of pages7
JournalIsrael Journal of Chemistry
Volume6
Issue number1
DOIs
StatePublished - 1968

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